Commercial nanofiltration membranes of different molecular weight cut-offs were tested on a pilot plant for the exploration of permeation nature of Ca, Mg, Mn, Fe, Na and ammonium ions. Correlation of transmembrane pressure and rejection quotient versus volumetric flux efficiency on nanofiltration membrane rejection and permeability behavior toward hydrated divalent and monovalent ions separation from the natural groundwater was observed. Membrane ion rejection affinity (MIRA) dimension was established as normalized TMP with regard to permeate solute moiety representing pressure value necessary for solute rejection change of 1%.
View Article and Find Full Text PDFJ Environ Sci Health A Tox Hazard Subst Environ Eng
December 2017
Different plant raw materials (corn stalk, wheat straw, saw dust, corn cobs, broom grass and Sudan grass) were carbonized and secondary activated in the rotating kiln with the action of water vapor as activation agent under different temperatures and lasting times. Optimum carbonization parameters such as temperature and lasting time were found to be 750°C and 45 min, while optimal conditions for powdered activated carbon obtained by water vapor activation at a temperature of 1,000 C and contact time of 120 min were determined. All obtained activated carbons were distinctly macroporous with mercury intrusion total specific pore volume in the range from 2.
View Article and Find Full Text PDFJ Environ Sci Health A Tox Hazard Subst Environ Eng
October 2016
The adsorption characteristics of synthetic zeolite CR-100 in a fixed-bed system using continuous flow of groundwater containing elevated ammonia concentration were examined. The possibilities for adsorbent mass calculation throughout mass transfer zone using novel mathematical approach as well as zeolite adsorption capacity at every sampling point in time or effluent volume were determined. The investigated adsorption process consisted of three clearly separated steps indicated to sorption kinetics.
View Article and Find Full Text PDFEnviron Sci Pollut Res Int
September 2016
The aim of this study was to investigate the performances of polyamide nanofiltration membranes during water reclamation. The study was conducted using nanofiltration concentrates obtained from two different nanofiltration drinking water treatment plants placed in the northern part of Serbia (Kikinda and Zrenjanin). Used nanofiltration concentrates contained high concentrations of arsenic (45 and 451 μg/L) and natural organic matter (43.
View Article and Find Full Text PDFJ Environ Sci Health A Tox Hazard Subst Environ Eng
October 2011
A pilot-scale study was performed to explore the possibility of the removal of natural organic matter (NOM) and arsenic from groundwater in the village of Melenci (Northern Serbia) using strongly basic, macroporous ion-exchange resin, commercially available as Amberlite IRA 958-Cl. The influences of the specific flow rate (SFR) and a broad range of contact times were studied using native groundwater and the same water pretreated with sodium hypochlorite (NaClO) for the oxidation of As(III) to As(V) and the degradation of NOM. The investigated SFR exceeded the manufacturer's recommended maximum value by up to ten times.
View Article and Find Full Text PDFThe removal of ammonium from the Valpovo region ground water (VGW) with the use of natural clinoptilolite samples from the Donje Jesenje deposit (Croatia) and the Zlatokop deposit in Vranjska Banja (Serbia) was studied. The natural Serbian (SZ) and Croatian zeolites (CZ) were transformed to the Na-form (Na-CZ and Na-SZ) in order to increase the exchange capacity of zeolite. The CZ and SZ theoretic ammonium sorption capacities were 24.
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