Hydrodynamic approximations for driven dense colloidal mixtures in narrow pores.

The system of driven dense colloid mixtures is studied in one-, two-, and three-dimensional geometries. We calculate the diffusion coefficients and mobilities for each particle type, including cross-terms, in a hydrodynamic limit, using a mean-field-type approximation. The set of nonlinear diffusion equations are then solved.

Short-range and long-range correlations in driven dense colloidal mixtures in narrow pores.

The system of a driven dense colloid mixture in a tube with diameter comparable to particle size is modeled by a generalization of the asymmetric simple exclusion process (ASEP) model. The generalization goes in two directions: relaxing the exclusion constraint by allowing several (but few) particles on a site and by considering two species of particles, which differ in size and transport coefficients. We calculate the nearest-neighbor correlations using a variant of the Kirkwood approximation and show by comparison with numerical simulations that the approximation provides quite accurate results.

Separation of dense colloidal suspensions in narrow channels: A stochastic model.

The flow of a colloidal suspension in a narrow channel of periodically varying width is described by the one-dimensional generalized asymmetric exclusion process. Each site admits multiple particle occupancy. We consider particles of two different sizes.

Kinetics of step bunching during growth: a minimal model.

We study a minimal stochastic model of step bunching during growth on a one-dimensional vicinal surface. The formation of bunches is controlled by the preferential attachment of atoms to descending steps (inverse Ehrlich-Schwoebel effect) and the ratio d of the attachment rate to the terrace diffusion coefficient. For generic parameters (d>0) the model exhibits a very slow crossover to a nontrivial asymptotic coarsening exponent beta approximately 0.