Estimation of parameters obtained by electrochemical impedance spectroscopy on systems containing high capacities.

Electrochemical systems with high capacities demand devices for electrochemical impedance spectroscopy (EIS) with ultra-low frequencies (in order of mHz), that are almost impossible to accomplish with analogue techniques, but this becomes possible by using a computer technique and accompanying digital equipment. Recently, an original software and hardware for electrochemical measurements, intended for electrochemical systems exhibiting high capacities, such as supercapacitors, has been developed. One of the included methods is EIS.

Hardware and Software of a Bipolar Current Source Controlled by PC.

This paper describes a realization of a bipolar current source developed by the paper's authors. The source is intended for use in galvanic and other industrial plants, where a pulse-reverse current supply (with the desired shape in time) is required. A prototype of the device, which provides the outcome current intensity up to ± 50 A, has been constructed.