J Environ Sci Health A Tox Hazard Subst Environ Eng
July 2006
This work aimed at studying the electrochemical reduction of the hexavalent chromium Cr(VI) by means of a tubular reactor operating under both continuous and batch regimes. It is shown that chromium (VI) reduction to chromium (III) was exerted not only by the oxidation of iron to Fe(II) released from the steel sacrifice anodes immersed in an acid solution to aid the overall process. Also, it is shown that there was an additional contribution to chromium reduction from an ancillary reaction at the cathode, where Fe(III) ions generated after the Cr(VI) reduction are again reduced to Fe(II), this being interpreted as a catalytic effect taking place.
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