Spatiotemporal distribution and human health risk assessment of potential toxic species in soils of urban and surrounding crop fields from an agricultural area, Córdoba, Argentina.

The spatiotemporal distribution of potentially toxic species was studied in the topsoil of parks, playgrounds, and surrounding crop fields of Marcos Juarez City in Córdoba province, Argentina. The content of available metals and of some pesticides used in the region was determined. The mean values of available metal concentrations in all samples, expressed in mg kg, were 7.

Validation of a continuous flow method for the determination of soluble iron in atmospheric dust and volcanic ash.

Iron is an essential micronutrient for phytoplankton growth and is supplied to the remote areas of the ocean mainly through atmospheric dust/ash. The amount of soluble Fe in dust/ash is a major source of uncertainty in modeling-Fe dissolution and deposition to the surface ocean. Currently in the literature, there exist almost as many different methods to estimate fractional solubility as researchers in the field, making it difficult to compare results between research groups.

Determination of phenol, resorcinol and hydroquinone in air samples by synchronous fluorescence using partial least-squares (PLS).

The determination of phenolic compounds is of great importance owing to their high toxicity. Some of them are present in tobacco smoke and it is important for their monitoring in air of closed room. A simple, rapid and sensitive method was developed for simultaneous determination of hydroquinone, resorcinol and phenol in this kind of samples.

A sensitive spectrophotometric method for lead determination by flow injection analysis with on-line preconcentration.

A new flow injection (FI) system for the determination of Pb(II) at trace level with a preconcentration step and spectrophotometric detection is proposed. It is based on preconcentration of lead ions on chitosan and dithizone-lead complex formation in aqueous medium (pH 9). The chemicals and FIA variables influencing the performance of the system were optimized and applied to the determination of lead in natural, well, and drinking water samples.

New automatized method with amperometric detection for the determination of azithromycin.

A FIA-amperometric method for azithromycin determination was developed. A working glassy carbon electrode and a Ag/AgCl/NaCl (3M) reference electrode were used. The determination is based on the electrochemical oxidation of the azithromycin at 0.

Enzymatic reverse FIA method for total phenols determination in urine samples.

A reverse flow injection spectrophotometric enzymatic method is proposed to quantify total phenols in urine samples. The polyphenol oxidase (PPO; EC 1.14.

Flow injection analysis: Rayleigh light scattering technique for total protein determination.

A novel flow injection analysis (FIA) method with Rayleigh light scattering (RLS) detection was developed for the determination of total protein concentrations. This method is based on the weak intensity of RLS of bromothymol blue (BB) (3',3"-dibromothymolsulfonephthalein) which can be enhanced by the addition of protein in weakly acidic solution. A common spectrofluorimeter was used as a detector.

Flow injection biamperometric determination of captopril.

An automated method to determine captopril (1-[(2S)-3-mercapto-2-methylpropionyl]-L-proline) is proposed. A flow injection manifold based on the indirect biamperometric detection of the captopril by using Fe(III)/Fe(II) as an indicating redox system and a Z-shaped flow-cell configuration, was developed. The calibration curve is linear over the range 0.