Interfacing Langmuir-Blodgett and Pickering Emulsions for the Synthesis of 2D Nanostructured Films: Applications in Copper Ion Adsorption.

This research focuses on developing a 2D thin film comprising a monolayer of silica nanoparticles functionalized with polyethyleneimine (PEI), achieved through a novel integration of Langmuir-Blodgett (L-B) and Pickering emulsion techniques. The primary aim was to create a nanostructured film that exhibits dual functionality: iridescence and efficient metal ion adsorption, specifically Cu(II) ions. The methodology combined L-B and Pickering emulsion polymerization to assemble and stabilize a nanoparticle monolayer at an oil/water interface, which was then polymerized under UV radiation to form an asymmetrically structured film.

Reversible Cu-Nanoparticle Formation in Soft Hydrogel Composites: Towards Write-Erase Displays and Fluorescence Detection.

In this study, we introduce a hydrogel-polymer microsphere (HPM) composite material constituted of PVA, glycerin, and polymer microspheres obtained from Pickering emulsions that are capable of adsorbing Cu ions. The obtained HPM composite is soft, flexible, can be fully saturated with Cu ions, and exhibits a reversible color transition from blue to black upon electrode contact or interaction with a reducing agent, due to in situ generation of copper nanoparticles (Cu-NPs). Because of the color contrast between the locally generated Cu-NPs and the background, the HPM can be used as substrate for stamping different shapes or writing text.

Morphological Design and Synthesis of Nanoparticles.

Nanoparticles are particles with dimensions measured in nanometers, and exist at a scale where the physical, chemical, and biological properties of materials can differ significantly from those at a larger scale [...

Water-Floating Hydrogel Polymer Microsphere Composites for Application in Hydrological Mining of Cu(II) Ions.

Innovative materials and technologies capable of extraction and recovery of technologically relevant metal ions from various water sources, such as lakes, oceans, ponds, or wastewater reservoirs, are in great demand. Polymer beads are among the most well-known solid-phase adsorbents and ion exchangers employed in metal ion recovery. On the other hand, hydrogels are an emerging platform for producing innovative adsorbents, which are environmentally friendly and biocompatible materials.

Development of Hybrid Materials Based on Chitosan, Poly(Ethylene Glycol) and Laponite RD: Effect of Clay Concentration.

In the context of increasing interest in biomaterials with applicability in cosmetics and medicine, this research aims to obtain and characterize some hybrid materials based on chitosan (CS) (antibacterial, biocompatible, and biodegradable), poly(ethylene glycol) (PEG) (non-toxic and prevents the adsorption of protein and cell) and Laponite RD (Lap) (bioactive). The rheological properties of the starting dispersions were investigated and discussed related to the interactions developed between components. All samples exhibited gel-like properties, and the storage modulus of CS/PEG dispersion increased from 6.