Nanoporous Conducting Polymer Nanowire Network-Encapsulated MnO-Based Flexible Supercapacitor with Enhanced Rate Capability and Cycling Stability.

Transition-metal-oxide-based electrochemical electrodes usually suffer from poor electron and ion transport, leading to deteriorated rate performance and cycling stability. Herein, we address these issues by developing a facile "conducting encapsulation" strategy toward a nanoporous PEDOT nanowire/MnO nanoparticle/PEDOT nanowire composite electrode. Through encapsulation of the PEDOT nanowire network, the overall electrochemical performance of the resultant composite electrode is substantially enhanced.

Nitrogen-Doped Porous Core-Sheath Graphene Fiber-Shaped Supercapacitors.

In this study, a strategy to fabricate nitrogen-doped porous core-sheath graphene fibers with the incorporation of polypyrrole-induced nitrogen doping and graphene oxide for porous architecture in sheath is reported. Polypyrrole/graphene oxide were introduced onto wet-spun graphene oxide fibers by dip-coating. Nitrogen-doped core-sheath graphene-based fibers (NSG@GFs) were obtained with subsequently thermally carbonized polypyrrole/small-sized graphene oxide and graphene oxide fiber slurry (PPY/SGO@GOF).

Three-Dimensional Hierarchically Porous Graphene Fiber-Shaped Supercapacitors with High Specific Capacitance and Rate Capability.

Chemically converted graphene fiber-shaped supercapacitors (FSSCs) are highly promising flexible energy storage devices for wearable electronics. However, the ultralow specific capacitance and poor rate performance severely hamper their practical applications. They are caused by severe stacking of graphene nanosheets and tortuous ion diffusion path in graphene-based electrodes; thus, the ultralow utilization of graphene has been rarely carefully considered to date.