Ultrafine particles play a crucial role in understanding climate change, mitigating adverse health effects, and developing strategies for air pollution control. However, the factors influencing the occurrence and development of new particle formation (NPF) events, as well as the underlying chemical mechanisms, remain inadequately explained. This study compared number concentrations and size distributions of atmospheric ultrafine particles at Xi'an (urban area) and the summit of Mt.
View Article and Find Full Text PDFOxygenated volatile organic compounds (OVOCs) play important roles in tropospheric chemistry, regulating the oxidation capacity and ozone (O) formation potential of the atmosphere. However, the evolution of OVOCs composition during vertical transport from the near surface to the upper atmosphere layer and the roles of OVOCs in the alpine atmospheric O formation are still poorly understood. In this study, we investigated the carbonyl compounds, the most important chemical group of OVOCs, and other gaseous pollutants simultaneously collected at the top (2060 m a.
View Article and Find Full Text PDFAerosol pH is not only a diagnostic indicator of secondary aerosol formation, but also a key factor in the specific chemical reaction routes that produce sulfate and nitrate. To understand the characteristics of aerosol acidity in the Mt. Hua, the chemical fractions of water-soluble inorganic ions in the atmospheric PM and size-resolved particle at the top and foot of Mt.
View Article and Find Full Text PDFGlyoxal and methylglyoxal are important volatile organic compounds in the atmosphere. The gas-particle partitioning of these carbonyl compounds makes significant contributions to O formation. In this study, both the gas- and particle-phase glyoxal and methylglyoxal concentrations at the foot and top of Mount Hua were determined simultaneously.
View Article and Find Full Text PDFDicarboxylic acids are one of the important water-soluble organic compounds in atmospheric aerosols, causing adverse effects to both climate and human health. More attention has therefore been paid to organic acids in aerosols. In this study, the molecular distribution and diurnal variations of wintertime dicarboxylic acids in a rural site of Guanzhong Plain, Northwest China, were explored.
View Article and Find Full Text PDFIn this study, 30 elements in fine particulate matter (PM) were measured in 18 Chinese cities in 2013. Elemental pollution in northern, southwest, and central China were severe, attributing to excessive coal and biomass combustion in these regions. The concentrations of S, Cl, and K in these areas were 8.
View Article and Find Full Text PDFBased on the enhancing effect of chitosan (CS) on luminol-dissolved oxygen chemiluminescence (CL) reaction, a flow injection (FI) luminol-CS CL system was established. It was found that the increase of CL intensity was proportional to the concentrations of CS ranging from 0.7 to 10.
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