A dendritic porous copper foam-carbonic anhydrase biohybrid for carbon dioxide electroreduction.

Carbonic anhydrase (CA) is bound to a dendritic porous copper foam (3D-Cu) electrostatic interaction to form a biohybrid (CA/3D-Cu), which exhibits high selectivity and Faraday efficiency in the electroreduction of carbon dioxide (CO) to formic acid (selectivity of 98.7%, Faraday efficiency of 82.1%) due to the large specific surface area of the 3D-Cu and the ultra-high CO hydration capacity of CA.