CeO -anchored β-Ni(OH) nanosheets onto nickel foam for efficient energy-saving hydrogen production an electrocatalytic glucose oxidation reaction.

Electrolytic glucose oxidation has garnered great interest in energy-saving hydrogen generation. However, high charge-transfer resistance and inefficient active centers have been recognized as the primary issues for poor electrochemical performance. In this study, for the first time, we offer a novel defect-rich CeO /β-Ni(OH) composite nanosheet-decorated Ni foam electrocatalyst (denoted as Ce@NF-GA), synthesized a unique hydrothermal approach under the co-participation of glycerol and acetic acid.

A glucose-assisted redox hydrothermal route to prepare a Mn-doped CeO catalyst for the total catalytic oxidation of VOCs.

In this study, a novel glucose-assisted redox hydrothermal method has been presented to prepare an Mn-doped CeO catalyst (denoted as Mn-CeO-R) for the first time. The obtained catalyst contains uniform nanoparticles with a small crystallite size, a large mesopore volume, and rich active surface oxygen species. Such features collectively contribute to improving the catalytic activity for the total catalytic oxidation of methanol (CHOH) and formaldehyde (HCHO).

Degradation of dyes by UV/Persulfate and comparison with other UV-based advanced oxidation processes: Kinetics and role of radicals.

This study investigated the degradation of methylene blue (MeB), methyl orange (MeO), and rhodamin B (RhB) by the UV/Persulfate (UV/PS) process. The dye degradation in the investigated UV-based Advanced Oxidation Processes (UV/AOPs) followed the first-order kinetic model. The second-order rate constant of the dyes with •OH, SO, and CO were calculated and found to be: k = 5.

Green synthesis of microalgae-based carbon dots for decoration of TiO nanoparticles in enhancement of organic dye photodegradation.

TiO is a well-known semiconductor used widely in the photocatalyst field, but its photocatalytic applications are hampered by a fast electron-hole recombination rate and low visible light absorption due to a wide-band-gap energy. Herein, we present a simple, low cost, and green approach to obtain carbon dots from microalgae, namely microalgae-based carbon dots (MCDs), using an unprecedented microwave-assisted treatment. The MCDs were successfully decorated on the surface of TiO nanoparticles.

Novel cryptomelane nanosheets for the superior catalytic combustion of oxygenated volatile organic compounds.

This work offers a novel pathway to prepare cryptomelane manganese oxides nanosheets as an superior catalyst for the catalytic combustion of oxygenated volatile organic compounds. The tunnel cryptomelane manganese oxides nanosheets were prepared from layered birnessite via simultaneously tuning pH and molar ratio (R) of the redox-precipitation between oxalic acid and KMnO. Thus, few-layered cryptomelane nanosheets possessing the most predominantly exposed (211) facet are generated at low pH (5.

Novel Architecture Titanium Carbide (TiCT) MXene Cocatalysts toward Photocatalytic Hydrogen Production: A Mini-Review.

Low dimensional transition metal carbide and nitride (MXenes) have been emerging as frontier materials for energy storage and conversion. TiCT was the first MXenes that discovered and soon become the most widely investigated among the MXenes family. Interestingly, TiCT exhibits ultrahigh catalytic activity towards the hydrogen evolution reaction.

Synthesis of Diatomite-Based Mesoporous Wool-Ball-Like Microspheres and Their Application for Toluene Total Oxidation Reaction.

Diatomite (DE) has attracted considerable attention owing to its abundance, low cost, and potential for a wide variety of applications. This work reports the development of mesoporous wool-ball-like (WBL) microspheres from natural DE through a simple hydrothermal treatment. We discovered that the presence of cetyltrimethylammonium bromide is a prerequisite for generating monodispersed WBL microspheres.