Mass-Selected Infrared Photodissociation Spectroscopic and Theoretical Insights into Nitrobenzene Dimer Anion Tagged by Argon.

The nitrobenzene dimer anion, NB, tagged with argon in the gas phase was successfully generated by using a collinear tandem time-of-flight mass spectrometer equipped with a supersonic ion source. Precise characterization was achieved through infrared photodissociation (IRPD) spectroscopy combining with theoretical calculation. Nine distinct absorptions were observed.

A TDDFT exploration on the excited-state intramolecular proton transfer in 2-(2'-hydroxyphenyl)-benzimidazole derivatives.

Excited-state intramolecular proton transfer (ESIPT) reactions are one of the fundamental energy transformation reactions in catalysis and biological process. The combining ESIPT with the twisted intramolecular charge transfer (TICT) brings the richness of optical, photoelectronic performances to certain functional compounds. Delineating the mechanism of ESIPT + TICT reactions and further understanding why a specific functional group dominates are fundamentally crucial for the design and application of the functionally photoelectric materials.

Insights into ESIPT-induced multicolor fluorescence emission in 2-(2'-hydroxy-5'-bromo)phenylbenzimidazole: a spectroscopic and TDDFT study.

Although multicolor luminescent materials are widely used in information encryption and decryption based on the excited-state intramolecular proton transfer (ESIPT) reaction, there remains a significant gap in the mechanistic understanding of how solvent and pH conditions influence the ESIPT process. Owing to their ability to avoid self-absorption as well as provide large Stokes' shift and strong emission properties, ESIPT-generated molecules (ESIPT gens) have recently emerged as highly potential fluorophores. Herein, the ESIPT mechanism of bromine-based (2'-hydroxy-5'-bromo)phenylbenzimidazole (HBI-pBr) was investigated in solvents using spectroscopic measurements and time-dependent density functional theory (TD-DFT) calculations.

A N-doped carbon substrate makes the Ru-Co alloy an efficient electrocatalyst for pH-universal seawater splitting.

Designing electrocatalysts for seawater splitting remains challenging. A Ru-Co alloy supported by an N-doped carbon substrate catalyst has been designed using etching and a low-temperature treatment method. Studies show that the superior performance of this catalyst is related to the hollow-structured N-doped carbon frame and surface reconstruction of the Ru-Co alloy.

Assessment of basic reproductive number for COVID-19 at global level: A meta-analysis.

Background: There are large knowledge gaps regarding how transmission of 2019 novel coronavirus disease (COVID-19) occurred in different settings across the world. This study aims to summarize basic reproduction number (R0) data and provide clues for designing prevention and control measures.

Methods: Several databases and preprint platforms were retrieved for literature reporting R0 values of COVID-19.

Environmental regulation and financial performance of Chinese listed companies.

Objective: The answer to this article lies in: Does the financial activities of physical enterprises have an adverse impact on their main business? Is it conducive to the sustainable development of the national economy? However, when most scholars study the impact of environmental regulations on companies performance, they have not classified companies performance. This article will study the relationship between environmental regulations and performance levels based on the classification of companies performance, and then divide the nature of industry pollution, companies location and nature of property for in-depth research.

Methods: First, this article uses a random effect variable-intercept model to measure companies financial performance and non-financial performance.

Effects of air pollutants on occurrences of influenza-like illness and laboratory-confirmed influenza in Hefei, China.

Accumulating evidence suggests that air pollution is a risk factor for adverse respiratory and cardiovascular health outcomes. However, the different impacts of exposure to air pollutants on influenza virus activity and influenza-like illness (ILI) have not been well documented in epidemiological studies. We examined the association between air pollutants of particular matters < 2.

Seasonal pattern of influenza activity in a subtropical city, China, 2010-2015.

Influenza seasonality study is critical for policy-makers to choose an optimal time for influenza vaccination campaign, especially for subtropical regions where influenza seasonality and periodicity are unclear. In this study, we explored the seasonality and periodicity of influenza in Hefei, China during 2010 to 2015 using five proxies originated from three data sources of clinical surveillance of influenza-like illness (ILI), laboratory surveillance of influenza and death registration of pneumonia and influenza. We combined both wavelets analysis and de-linear-trend regression with Fourier harmonic terms to estimate seasonal characteristics of epidemic phase, peak time, amplitude, ratio of dominant seasonality.

Excess mortality associated with influenza after the 2009 H1N1 pandemic in a subtropical city in China, 2010-2015.

Objectives: The aim of this study was to use a quasi-Poisson regression model to estimate the mortality burden associated with influenza type/subtypes in a subtropical city in China, for the years 2010-2015.

Methods: Quasi-Poisson models were fitted separately to weekly numbers of deaths from various causes. The exploratory variables were products of weekly proportions of specimens positive for influenza type/subtypes and weekly influenza-like illness consultation rates to represent influenza activity.