Microstructural evolution of bio-based chitosan aerogels for thermal insulator with superior moisture/fatigue resistance and anti-thermal-shock.

Bio-based aerogel is a functionalized nanoporous material with environmentally friendly, high surface area, ultra-low density, high porosity, and low thermal conductivity, making it suitable for various applications such as energy-saving buildings, electronic information, separation, adsorption, catalysis, biomedicine, and others. However, the current bio-based chitosan aerogel still faces great challenges in reaching multifunctional improvement to address its intrinsic shortcomings. Herein, we propose a new approach depending upon supramolecular interactions for constructing chitosan/bacterial cellulose aerogels that simultaneously possess superior moisture resistance/fatigue, anti-thermal-shock, and flame retardancy.

Double-Phase-Networking Polyimide Hybrid Aerogel with Exceptional Dimensional Stability for Superior Thermal Protection System.

Polyimide aerogels have been extensively used in thermal protection domain because they possess a combination of intrinsic characteristics of aerogels and unique features of polyimide. However, polyimide aerogels still suffer significant thermally induced shrinkage at temperatures above 200 °C, restricting their application at high temperature. Here, a novel "double-phase-networking" strategy is proposed for fabricating a lightweight and mechanically robust polyimide hybrid aerogel by forming silica-zirconia-phase networking skeletons, which possess exceptional dimensional stability in high-temperature environments and superior thermal insulation.

Deep Eutectic Solvents for Efficient and Selective Extraction of α-Glucosidase Inhibitors from Waste Seeds of Refined Betel Nuts.

During the production process of refined betel nuts in China, a large amount of processing by-product, betel nut waste seeds, is generated. Betel nut waste seeds are rich in bioactive elements, but they have not been effectively utilized yet. In this study, an ultrasonic-assisted deep eutectic solvent method (DES) was used to selectively extract α-glucosidase inhibitors from waste seeds.

MIHIC: a multiplex IHC histopathological image classification dataset for lung cancer immune microenvironment quantification.

Background: Immunohistochemistry (IHC) is a widely used laboratory technique for cancer diagnosis, which selectively binds specific antibodies to target proteins in tissue samples and then makes the bound proteins visible through chemical staining. Deep learning approaches have the potential to be employed in quantifying tumor immune micro-environment (TIME) in digitized IHC histological slides. However, it lacks of publicly available IHC datasets explicitly collected for the in-depth TIME analysis.

Comprehensive Evaluation of Polyaniline-Doped Lignosulfonate in Adsorbing Dye and Heavy Metal Ions.

Lignosulfonate/polyaniline (LS/PANI) nanocomposite adsorbent materials were prepared by the chemical polymerization of lignosulfonate with an aniline monomer as a dopant and structure-directing agent, and the adsorption behavior of dyes as well as heavy metal ions was investigated. LS/PANI composites were used as dye adsorbents for the removal of different cationic dyes (malachite green, methylene blue, and crystal violet). The adsorption behavior of LS/PANI composites as dye adsorbents for malachite green was investigated by examining the effects of the adsorbent dosage, solution pH, initial concentration of dye, adsorption time, and temperature on the adsorption properties of this dye.

Preparation of spherical porous carbon from lignin-derived phenolic resin and its application in supercapacitor electrodes.

Lignin is the most abundant aromatic biomass resource in nature and is the main by-product of paper industry and biorefinery industry, which has the characteristics of abundant source, renewable and low cost. Deep eutectic solvents (DES) are a nascent environmentally friendly solvent option that is gaining traction. DES composed of p-toluenesulfonic acid and choline chloride is used for batch treatment of alkaline lignin, and the bio-oil obtained is ternary polymerized with formaldehyde and phenol to obtain lignin phenolic resin.

Preparation of Symmetrical Capacitors from Lignin-Derived Phenol and PANI Composites with Good Electrical Conductivity.

As a natural polymer, lignin is only less abundant in nature than cellulose. It has the form of an aromatic macromolecule, with benzene propane monomers connected by molecular bonds such as C-C and C-O-C. One method to accomplish high-value lignin conversion is degradation.

Beating thermal noise in a dynamic signal measurement by a nanofabricated cavity optomechanical sensor.

Thermal fluctuations often impose both fundamental and practical measurement limits on high-performance sensors, motivating the development of techniques that bypass the limitations imposed by thermal noise outside cryogenic environments. Here, we theoretically propose and experimentally demonstrate a measurement method that reduces the effective transducer temperature and improves the measurement precision of a dynamic impulse response signal. Thermal noise-limited, integrated cavity optomechanical atomic force microscopy probes are used in a photothermal-induced resonance measurement to demonstrate an effective temperature reduction by a factor of ≈25, i.

Highly-twisted states of light from a high quality factor photonic crystal ring.

Twisted light with orbital angular momentum (OAM) has been extensively studied for applications in quantum and classical communications, microscopy, and optical micromanipulation. Ejecting high angular momentum states of a whispering gallery mode (WGM) microresonator through a grating-assisted mechanism provides a scalable, chip-integrated solution for OAM generation. However, demonstrated OAM microresonators have exhibited a much lower quality factor (Q) than conventional WGM resonators (by >100×), and an understanding of the limits on Q has been lacking.

Rod and slit photonic crystal microrings for on-chip cavity quantum electrodynamics.

Micro-/nanocavities that combine high quality factor () and small mode volume () have been used to enhance light-matter interactions for cavity quantum electrodynamics (cQED). Whispering gallery mode (WGM) geometries such as microdisks and microrings support high- and are design- and fabrication-friendly, but is often limited to tens of cubic wavelengths to avoid WGM radiation. The stronger modal confinement provided by either one-dimensional or two-dimensional photonic crystal defect geometries can yield sub-cubic-wavelength , yet the requirements on precise design and dimensional control are typically much more stringent to ensure high-.

Fractional Optical Angular Momentum and Multi-Defect-Mediated Mode Renormalization and Orientation Control in Photonic Crystal Microring Resonators.

Whispering gallery modes (WGMs) in circularly symmetric optical microresonators exhibit integer quantized angular momentum numbers due to the boundary condition imposed by the geometry. Here, we show that incorporating a photonic crystal pattern in an integrated microring can result in WGMs with fractional optical angular momentum. By choosing the photonic crystal periodicity to open a photonic band gap with a band-edge momentum lying between that of two WGMs of the unperturbed ring, we observe hybridized WGMs with half-integer quantized angular momentum numbers (m∈Z+1/2).

High Throughput Nanoimaging of Thermal Conductivity and Interfacial Thermal Conductance.

Thermal properties of materials are often determined by measuring thermalization processes; however, such measurements at the nanoscale are challenging because they require high sensitivity concurrently with high temporal and spatial resolutions. Here, we develop an optomechanical cantilever probe and customize an atomic force microscope with low detection noise ≈1 fm/Hz over a wide (>100 MHz) bandwidth that measures thermalization dynamics with ≈10 ns temporal resolution, ≈35 nm spatial resolution, and high sensitivity. This setup enables fast nanoimaging of thermal conductivity (η) and interfacial thermal conductance () with measurement throughputs ≈6000× faster than conventional macroscale-resolution time-domain thermoreflectance acquiring the full sample thermalization.

Persistent Nonlinear Phase-Locking and Nonmonotonic Energy Dissipation in Micromechanical Resonators.

Many nonlinear systems are described by eigenmodes with amplitude-dependent frequencies, interacting strongly whenever the frequencies become commensurate at internal resonances. Fast energy exchange via the resonances holds the key to rich dynamical behavior, such as time-varying relaxation rates and signatures of nonergodicity in thermal equilibrium, revealed in the recent experimental and theoretical studies of micro- and nanomechanical resonators. However, a universal yet intuitive physical description for these diverse and sometimes contradictory experimental observations remains elusive.

Overcoming thermo-optical dynamics in broadband nanophotonic sensing.

Advances in integrated photonics open up exciting opportunities for batch-fabricated optical sensors using high-quality-factor nanophotonic cavities to achieve ultrahigh sensitivities and bandwidths. The sensitivity improves with increasing optical power; however, localized absorption and heating within a micrometer-scale mode volume prominently distorts the cavity resonances and strongly couples the sensor response to thermal dynamics, limiting the sensitivity and hindering the measurement of broadband time-dependent signals. Here, we derive a frequency-dependent photonic sensor transfer function that accounts for thermo-optical dynamics and quantitatively describes the measured broadband optomechanical signal from an integrated photonic atomic force microscopy nanomechanical probe.

Dihydro-Si-rhodamine for live-cell localization microscopy.

Fluorophores with photo-modulatory fluorescence properties are valuable for cutting-edge localization microscopy. The existing probes are either photo-activatable, or photo-switchable, but not both. We report a probe (DH-SiR), a leuco-dye obtained by reduction of Si-rhodamine, with both photo-activatable and photo-switchable fluorescence.

Using thermo-optical nonlinearity to robustly separate absorption and radiation losses in nanophotonic resonators.

Key for optical microresonator engineering, the total intrinsic loss is easily determined by spectroscopy; however, quantitatively separating absorption and radiative losses is challenging, and there is not a general and robust method. Here, we propose and experimentally demonstrate a general all-optical characterization technique for separating the loss mechanisms with high confidence using only linear spectroscopic measurements and an optically measured resonator thermal time constant. We report the absorption, radiation, and coupling losses for ten whispering-gallery modes of three different radial orders on a Si microdisk.

Strong geometry dependence of the Casimir force between interpenetrated rectangular gratings.

Quantum fluctuations give rise to Casimir forces between two parallel conducting plates, the magnitude of which increases monotonically as the separation decreases. By introducing nanoscale gratings to the surfaces, recent advances have opened opportunities for controlling the Casimir force in complex geometries. Here, we measure the Casimir force between two rectangular silicon gratings.

Fundamental limits and optimal estimation of the resonance frequency of a linear harmonic oscillator.

All physical oscillators are subject to thermodynamic and quantum perturbations, fundamentally limiting measurement of their resonance frequency. Analyses assuming specific ways of estimating frequency can underestimate the available precision and overlook unconventional measurement regimes. Here we derive a general, estimation-method-independent Cramer Rao lower bound for a linear harmonic oscillator resonance frequency measurement uncertainty, seamlessly accounting for the quantum, thermodynamic and instrumental limitations, including Fisher information from quantum backaction- and thermodynamically-driven fluctuations.

Frequency Stabilization of Nanomechanical Resonators Using Thermally Invariant Strain Engineering.

Microfabricated mechanical resonators enable precision measurement techniques from atomic force microscopy to emerging quantum applications. The resonance frequency-based physical sensing combines high precision with long-term stability. However, widely used SiN resonators suffer from frequency sensitivity to temperature due to the differential thermal expansion vs the Si substrates.

Giant Casimir Torque between Rotated Gratings and the θ=0 Anomaly.

We study the Casimir torque between two metallic one-dimensional gratings rotated by an angle θ with respect to each other. We find that, for infinitely extended gratings, the Casimir energy is anomalously discontinuous at θ=0, due to a critical zero-order geometric transition between a 2D- and a 1D-periodic system. This transition is a peculiarity of the grating geometry and does not exist for intrinsically anisotropic materials.