In-Situ Cross-linked F- and P-Containing Solid Polymer Electrolyte for Long-Cycling and High-Safety Lithium Metal Batteries with Various Cathode Materials.

The practical application of lithium metal batteries (LMBs) has been hindered by limited cycle-life and safety concerns. To solve these problems, we develop a novel fluorinated phosphate cross-linker for gel polymer electrolyte in high-voltage LMBs, achieving superior electrochemical performance and high safety simultaneously. The fluorinated phosphate cross-linked gel polymer electrolyte (FP-GPE) by in-situ polymerization method not only demonstrates high oxidation stability but also exhibits excellent compatibility with lithium metal anode.

An In Situ Fabricated Graphene/Bipolar Polymer Hybrid Material Delivers Ultralong Cycle Life over 15 000 Cycles as a High-Performance Electrode Material.

Organic electrode materials are promising for the future energy storage systems owing to their tunable structures, abundant resources, and environmental friendliness. Many advanced lithium-ion batteries with organic electrodes have been developed and show excellent performance. However, developing organic materials with overall superior performance still faces great challenges, such as low capacity, poor stability, inferior conductivity, and low utilization of active sites.