The structural coloration of textiles with bionic photonic crystals (PCs) is expected to become a critical approach to the ecological coloration of textiles. Rapid and large-area preparation of PC structurally colored textiles can be achieved via self-assembly of high mass fractions of liquid photonic crystals (LPCs). However, the rapid and large-scale manufacturing of LPCs remains a challenge.
View Article and Find Full Text PDFPatterned structural color photonic crystals (PCs) based on periodic photonic nanostructures have attracted great interest in developing high-performance sensors and other smart optical materials as well as tunable structurally colored fashion textiles. However, previously reported patterned PCs with both high color saturation and tough mechanical strength were difficult to achieve, which restricts their practical applications. Herein, arbitrarily patterned silica/polyurethane acrylate (SiO/PUA) inverse opal photonic crystals (IOPCs) with high color saturation and tough mechanical strength were innovatively designed and fabricated by writing with photopolymerizable PUA "ink" on a self-assembled hollow SiO PC template.
View Article and Find Full Text PDFACS Appl Mater Interfaces
December 2015
Constructing nanoscale hybrid materials with unique interfacial structures by using various metal oxides and carbon supports as building blocks are of great importance to develop highly active, economical hybrid catalysts for oxygen reduction reaction (ORR). In this work, La2O2CO3 encapsulated La2O3 nanoparticles on a carbon black (La2O2CO3@La2O3/C) were fabricated via chemical precipitation in an aqueous solution containing different concentrations of cetyltrimethyl ammonium bromide (CTAB), followed by calcination at 750 °C. At a given CTAB concentration 24.
View Article and Find Full Text PDFGuang Pu Xue Yu Guang Pu Fen Xi
February 2003
The surface-enhanced Raman scattering (SERS) spectra of adenine, purine and pyrene adsorbed on a SERS-active silver surface roughened by nitric acid have been measured over the -190 degrees C-30 degrees C surface temperature range. The results show that the Raman shifts and SERS intensity of the vibrations, which are enhanced by electromagnetic mechanism, are affected by temperature, those by chemical mechanism are not. However, it has been found that the observed temperature dependence can be explained by postulating the reorientation of the absorbates.
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