A versatile steel belt casting equipment for in situ synchrotron radiation x-ray scattering measurement of polymer films.

A steel belt casting equipment, weighing approximately ∼6-7 tons and measuring ∼5 m in length, has been designed and developed for simulating the industrial processing of polymer films and being combined with synchrotron radiation in situ x-ray scattering measurements. Through modification of its modules, it is feasible to implement two distinct film casting modes, namely the wet and the dry casting processes. The speed of a steel belt can span from 0.

Tuning 3D refractive indices via constrained uniaxial stretch in cellulose triacetate films plasticized with triethyl citrate.

Tuning 3D refractive indices of polymers is urgently needed for optical films, but it is quite challenging. Here, we proposed a simple constrained uniaxial stretch method that successfully tuned the 3D refractive indices in cellulose triacetate (TAC) films plasticized with triethyl citrate (TEC). Our results suggest that, under constrained uniaxial stretch, the main chains and side groups prefer to orientate in the stretch direction and the constrained direction, respectively.

Regulation of orientation birefringence for cellulose acetate film: The role of crystallization and orientation.

Cellulose acetate (CA) based films are widely used in liquid crystal displays due to their outstanding transparency, and a certain orientation birefringence of CA films is required when they are used as retardation films. The regulation of orientation birefringence is usually from the perspective of stretch-induced orientation, while the effects of crystallization behaviors of CA films remain obscure. In this study, the roles of crystallization and orientation on the orientation birefringence of CA films were elucidated.

Effects of shear on epitaxial crystallization of poly(ε-caprolactone) on reduced graphene oxide.

Epitaxial crystallization of poly(ε-caprolactone) (PCL) on reduced graphene oxide (RGO) was investigated by shearing at different shear rates of 3 s and 75 s and different shear temperatures of 65 °C, 70 °C and 75 °C, respectively. Two dimensional wide angle X-ray diffraction (2D WAXD) results show that the crystallinity and the orientation degrees of the (110) plane of PCL/RGO nanocomposites with shear are higher than those without shear, but the imposed shear field has no obvious effect on the crystal structure of the PCL matrix. Two dimensional small angle X-ray scattering (2D SAXS) results suggest that the imposed shear field makes PCL chains epitaxially crystallize on RGO surfaces to form thicker lamellae.