Can the pH-dependent adsorption of phenoxyalkanoic herbicides in soils be described with a single equation?

The six phenoxyalkanoic acid herbicides currently used in the European Union have similar molecular structures. Therefore, we assumed the soil components involved in the adsorption mechanisms of these herbicides to be identical. The values of the adsorption distribution coefficient K, obtained via batch experiments involving typical Polish Arenosol, Luvisol, and Chernozem profiles with a native pH of 4.

The Optical and Spectroscopic Properties of Fuchsite, Spodumene, and Lepidolite from Northern Scandinavia (Kautokeino, Kaustinen, Kolmozero).

Li-Ce-Ta (LCT) pegmatites containing lithium mineralization in the form of spodumene and lepidolite, as well as fuchsite, from the regions of northern Scandinavia (N Norway, N Finland, N Russia) were studied. Detailed analyses of the chemical compositions of these minerals were carried out, involving scanning electron microscopy (SEM) with energy-dispersive spectroscopy (EDS), Fourier transform infrared (FTIR) spectroscopy with attenuated total reflectance (ATR), and X-ray photoelectron spectroscopy (XPS) studies. Their crystal structures were confirmed with the X-ray diffraction technique.

Lake microbiome and trophy fluctuations of the ancient hemp rettery.

Lake sediments not only store the long-term ecological information including pollen and microfossils but are also a source of sedimentary DNA (sedDNA). Here, by the combination of traditional multi-proxy paleolimnological methods with the whole-metagenome shotgun-sequencing of sedDNA we were able to paint a comprehensive picture of the fluctuations in trophy and bacterial diversity and metabolism of a small temperate lake in response to hemp retting, across the past 2000 years. Hemp retting (HR), a key step in hemp fibre production, was historically carried out in freshwater reservoirs and had a negative impact on the lake ecosystems.

Origin and occurrence of gem-quality, skarn-hosted barite from Jebel Ouichane near Nador in Morocco.

Light-blue barite from Jebel Ouichane in Morocco forms blade-like tabular crystals (up to ca. 10 cm) with superb transparency and lustre and represents one of the most spectacular gem-quality worldwide. The barite is hosted by iron-ore-bearing skarns, developed within Jurassic-Cretaceous limestones, and occurs in close spatial association with calcite.

Adsorption of bentazone in the profiles of mineral soils with low organic matter content.

The current laboratory adsorption study aimed at determination of the values of adsorption distribution coefficient (Kd) of bentazone in the profiles of Arenosols, Luvisols, and Cambisols, which are the most common arable mineral soils in Poland. The study attempted to identify the soil components that bind bentazone and the principal adsorption mechanisms of this compound as well as create a model capable of predicting its adsorption in soils. The Kd values determined in batch experiments after 24 h of shaking were very low, and ranged from 0.