Chlorido{2-[(dimethyl-amino)-methyl]phenyl-κC,N}(1-methyl-1H-imidazole-κN)palladium(II).

In the title compound, [Pd(C(9)H(12)N)Cl(C(4)H(6)N(2))], which was synthesized from the reaction of 1-methyl-imidazole with dimeric dichloridobis[2-(dimethyl-amino)-benz-yl]palla-dium(II), the ring-deprotonated N,N-dimethyl-benzyl-amine ligand acts in a C,N-bidentate fashion. The dihedral angle between the ring of the 1-methyl-imidazole ligand and the palladacycle plane is 57.88 (16)°.

catena-Poly[[[diaqua-(nitrato-κO,O')(2,2':6',2''-terpyridine-κN,N',N'')ytterbium(III)]-μ-cyanido-κN:C-[dicyanido-platinum(II)]-μ-cyanido-κC:N] acetonitrile monosolvate].

The title compound, {[PtYb(CN)(4)(NO(3))(C(15)H(11)N(3))(H(2)O)(2)]·CH(3)CN}(n), was isolated from solution as a one-dimensional coordination polymer. The Yb(3+) site has ninefold coordination with a distorted tricapped trigonal-prismatic geometry, while the Pt(II) ion is coordinated by four cyanide groups in an almost regular square-planar geometry. cis-Bridging by the tetra-cyanidoplatinate(II) anions links the Yb(3+) cations, forming chains.

Sesquicaesium hemisodium tetra-cyanidoplatinate(II) sesquihydrate.

The title compound, Cs(1.5)Na(0.5)[Pt(CN)(4)]·1.