Publications by authors named "Milan M Antonijevic"

Cadmium is one of the most dangerous pollutants found in the environment, where it exists mainly due to human activities. High cadmium concentrations can cause serious problems, which is why the detection and determination of Cd is one of the most important tasks. Electroanalytical methods provide rapid and accurate results in the detection of cadmium in various solutions.

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  • Determining target analytes, like caffeine, at low concentrations is crucial in industries such as pharmaceuticals, environmental protection, and food safety due to both their benefits and potential negative effects.
  • Electrochemical methods using sensors, especially those based on carbon materials, are favored for their efficiency, speed, affordability, and ease of use.
  • This review summarizes current literature on the development and enhancement of electrochemical sensors for accurate caffeine detection.
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  • - This research aimed to create a non-toxic and cost-effective electrochemical sensor for detecting L-tryptophan, utilizing a graphite rod from zinc-carbon batteries to tackle electronic waste.
  • - Two electrochemical methods, differential pulse voltammetry and cyclic voltammetry, were employed, revealing that the oxidation of L-tryptophan is influenced by pH, with optimal response at pH 4.0, and operates as an irreversible two-electron/two-proton reaction.
  • - The sensor demonstrated reliable detection capabilities, with a limit of detection at 1.73 µM and a quantification limit at 5.78 µM, successfully analyzing L-tryptophan in milk and apple
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This paper aims to examine the efficiency of 5-chlorobenzotriazole (5Cl-BTA) as a copper corrosion inhibitor in acidic rain solutions with a pH value of 2.42 by the electrochemical polarization method. 5-Chlorobenzotriazole acts similar to a mixed type inhibitor, according to the potentiodynamic polarization measurements.

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  • Titanium is a widely used biomaterial, and this study examines how adenine, thymine, and l-histidine affect its corrosion in simulated body solutions.
  • Various electrochemical techniques revealed that these biomolecules enhance titanium's corrosion resistance by forming a stable protective film on its surface.
  • Quantum chemical calculations supported the electrochemical findings, suggesting that adenine, thymine, and l-histidine could serve as effective corrosion inhibitors for titanium.
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The effects of adenine, salicylaldoxime and 4(5)-methylimidazole on brass corrosion in NaCl were investigated. The investigation comprised electrochemical techniques, scanning electron microscopy and quantum chemical calculation. The results obtained by polarization measurements show that the examined compounds successfully inhibited the corrosion of brass.

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It is known that if unused drugs are improperly disposed, they can pollute the environment. Furthermore, researchers are still trying to find an environmentally friendly corrosion inhibitor. These factors lead to the possible application of unused pharmaceutical compounds as corrosion inhibitors.

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In this study, the samples of the spatial soil and organs of the grapevine (Vitis vinifera) cultivar Tamjanika were collected from the selected zones near the Mining and Smelting Complex Bor (East Serbia). They were analyzed by ICP-OES to determine the content of Cu, Zn, Pb, As, Cd, and Ni with the aim of ascertaining if these data may help in the assessment and improvement of the quality of environment in polluted areas such as Bor and its surrounding area. The results obtained from the calculated biological and enrichment factors, as well as from the Pearson correlation study and hierarchical cluster analysis confirmed that very useful information is recorded in plant organs: root, stem, leaves, and fruit.

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The aim of this study was to investigate electrochemical properties of brass in neutral and weakly alkaline solutions in the presence of cysteine as a nontoxic and ecological corrosion inhibitor. Potentiodynamic measurements, open circuit potential measurements, as well as chronoamperometric measurements were the methods used during investigation of the inhibitory effect of cysteine on the corrosion behaviour of brass. Potentiodynamic measurements showed that cysteine behaves as a mixed-type inhibitor in the investigated media.

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Determination of a pyrite contaminated soil texture, content of heavy metals in the soil and soil pH, was the aim in the investigation. Acidification of damaged soil was corrected by calcium carbonate. Mineral nutrients and organic matter (NPK, dung, earthworm cast, straw and coal dust) were added to damaged soil.

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