Publications by authors named "Mikhail Shuba"

Article Synopsis
  • This paper introduces a deep learning method for detecting and classifying organic water pollutants, specifically hydroquinone and benzoquinone, which are tough to distinguish due to similar electroactivity.
  • The detection is performed using low-cost, disposable screen-printed electrodes combined with cyclic voltammetry techniques enhanced by nanomaterials like carbon nanotubes, improving sensitivity by about 25 times.
  • The analysis results are transformed into RGB images through Gramian angular field transformations, allowing a convolutional neural network to achieve 100% accuracy in classifying the pollutants.
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Water pollution is nowadays a global problem and the effective detection of pollutants is of fundamental importance. Herein, a facile, efficient, robust, and rapid (response time < 2 min) method for the determination of important quinone-based industrial pollutants such as hydroquinone and benzoquinone is reported. The recognition method is based on the use of screen-printed electrodes as sensing platforms, enhanced with carbon-based nanomaterials.

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Single-walled carbon nanotubes (SWCNTs) demonstrate a strong potential as an optically activated theranostic nano-agent. However, using SWCNTs in theranostics still requires revealing mechanisms of the SWCNT-mediated effects on cellular functions. Even though rapid and delayed cellular responses can differ significantly and may lead to undesirable consequences, understanding of these mechanisms is still incomplete.

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Article Synopsis
  • The study investigates how an external electric field affects the behavior of single-walled carbon nanotubes (SWCNTs) in glioma cells, focusing on their accumulation, distribution, and clumping.
  • C6 glioma cells were treated with SWCNTs and exposed to specific electric pulses, finding that the electric field enhances the uptake of nanotubes by the cells.
  • Results showed a significant increase in the number of nanotubes within cell agglomerates after electric field stimulation, suggesting that this method could improve the effectiveness of delivering anticancer drugs while reducing the required doses.
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The composites and thin films comprising individual single-walled carbon nanotubes with a polymer coating (p-CNTs) have been prepared and their electromagnetic responses have been studied in a wide range from low-frequency (25-10 Hz) up to the infrared region. In spite of the high volume fraction of the nanotubes (up to 3.3%), the polymer coating prevents direct p-CNT contacts and the formation of the percolation network in those composites, so that p-CNTs interact only via the electromagnetic coupling.

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The electrical properties of conducting meshes are investigated numerically by solving the related Kirchhoff equations with the Lanczos algorithm. The method is directly inspired by the recursion technique widely used to study the electronic and vibrational spectra of solids. The method is demonstrated to be very efficient and fast when applied to resistor networks.

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The excitation of modes of an open-face slab waveguide by light incident on a thin-film photovoltaic solar cell with a periodically corrugated metal backreflector is indicated by peaks in the absorptance spectrum. An absorptance peak due to the excitation of a waveguide mode (WGM) can split as the corrugation depth increases. The splitting can be explained in terms of the wavenumbers of the WGMs of two open-face slab waveguides with different thicknesses of the semiconductor layer.

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The rigorous coupled-wave approach (RCWA) is extensively used to compute optical absorption and photon absorption in thin-film photovoltaic solar cells backed by 1D metallic gratings when the wave vector of the incident light lies wholly in the grating plane. The RCWA algorithm converges rapidly for incident s-polarized light over the entire 400-1100 nm solar spectrum. It also performs well for incident p-polarized light in the 400-650 nm spectral regime, but even with a large number of Floquet harmonics in the solution, the total reflectance is underestimated in the 650-1100 nm spectral regime.

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Electromagnetic absorption and subsequent heating of nanoparticle solutions and simple NaCl ionic solutions is examined for biomedical applications in the radiofrequency range at 13.56 MHz. It is shown via both theory and experiment that for in vitro measurements the shape of the solution container plays a major role in absorption and heating.

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