The paper presents a study concerning the role of ferroelectric filler size and clustering in the dielectric properties of 20%BaTiO-80%PVDF and of 20% (2%Ag-98%BaTiO)-PVDF hybrid nanocomposites. By finite element calculations, it was shown that using fillers with ε > 10 does not provide a permittivity rise in the composites and the effective dielectric constant tends to saturate to specific values determined by the filler size and agglomeration degree. Irrespective of the ferroelectric filler sizes, the addition of metallic ultrafine nanoparticles (Ag) results in permittivity intensification and the effect is even stronger if the metallic nanoparticles are connected to a higher degree with the ferroelectric particles' surfaces.
View Article and Find Full Text PDFThe role of Ag addition on the structural, dielectric, and mechanical harvesting response of 20%(Ag - (1 - )BaTiO) - 80%PVDF ( = 0, 2, 5, 7 and 27 vol.%) flexible composites is investigated. The inorganic fillers were realized by precipitating fine (~3 nm) silver nanoparticles onto BaTiO nanoparticles (~60 nm average size).
View Article and Find Full Text PDFThe frequency and temperature dependence of dielectric properties of CHNHPbI (MAPI) crystals have been studied and analyzed in connection with temperature-dependent structural studies. The obtained results bring arguments for the existence of ferroelectricity and aim to complete the current knowledge on the thermally activated conduction mechanisms, in dark equilibrium and in the presence of a small external a.c.
View Article and Find Full Text PDFThe discovery of multifunctional properties related to electro-activity of organic systems of biomolecules is important for a variety of applications, especially for devices in the realm of biocompatible sensors and/or bioactuators. A further step towards such applications is to prepare thin films with the required properties. Here, the investigation is focused on the characterization of films of guanine and cytosine nucleobases, prepared by thermal evaporation-an industrial accessible deposition technique.
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