Microchemical analysis of Leonardo da Vinci's lead white paints reveals knowledge and control over pigment scattering properties.

Leonardo da Vinci (1452-1519) is a key artistic and scientific figure of the Renaissance. He is renowned for his science of art, taking advantage of his acute observations of nature to achieve striking pictorial results. This study describes the analysis of an exceptional sample from one of Leonardo's final masterpieces: The Virgin and Child with St.

Toward a multimodal fusion of layered cultural object images: complementarity of optical coherence tomography and terahertz time-domain imaging in the heritage field.

Terahertz time-domain imaging (THz-TDI) and spectral-domain optical coherence tomography (SD-OCT) are two techniques capable of providing 3D datasets from which depth profiles and cross-sectional images of an object can be derived. They are novel photonics technologies of particular relevance to the field of heritage science, for which the comprehension of the stratigraphic structure of a cultural heritage object may help in the understanding of its artistic technology and state of preservation. The differences in imaging depth, field of view, and axial/lateral resolutions of the two imaging techniques provide different but complementary information of the same scene.

Revealing the Origin and History of Lead-White Pigments by Their Photoluminescence Properties.

The lead white pigment, composed of two main mineral phases cerussite PbCO and hydrocerussite 2PbCO·Pb(OH), has been used in paintings since the Antiquity. The study of historical sources revealed that a large variety of lead white qualities were proposed, depending on the degree of sophistication of the pigment synthesis. Investigation of photoluminescence of the two constitutive mineral phases gave insight into the origin of the visible emission of these materials and emphasized the influence of structural defects on their photoluminescence properties.

Degradation process of lead chromate in paintings by Vincent van Gogh studied by means of spectromicroscopic methods. Part 5. Effects of nonoriginal surface coatings into the nature and distribution of chromium and sulfur species in chrome yellow paints.

The darkening of lead chromate yellow pigments, caused by a reduction of the chromate ions to Cr(III) compounds, is known to affect the appearance of several paintings by Vincent van Gogh. In previous papers of this series, we demonstrated that the darkening is activated by light and depends on the chemical composition and crystalline structure of the pigments. In this work, the results of Part 2 are extended and complemented with a new study aimed at deepening the knowledge of the nature and distribution of Cr and S species at the interface between the chrome yellow paint and the nonoriginal coating layer.

Terahertz time-domain imaging of hidden defects in wooden artworks: application to a Russian icon painting.

We use terahertz time-domain imaging and time-of-flight tomography to examine subsurface defects in an early-19th-century Russian icon painting. In the transmission geometry, we distinguish between native wood and higher-absorption knotted wood. In reflection, we identify a void in the wood filled with foreign filler material.

Sub-surface terahertz imaging through uneven surfaces: visualizing Neolithic wall paintings in Çatalhöyük.

Pulsed terahertz imaging is being developed as a technique to image obscured mural paintings. Due to significant advances in terahertz technology, portable systems are now capable of operating in unregulated environments and this has prompted their use on archaeological excavations. August 2011 saw the first use of pulsed terahertz imaging at the archaeological site of Çatalhöyük, Turkey, where mural paintings dating from the Neolithic period are continuously being uncovered by archaeologists.

Terahertz deconvolution.

The ability to retrieve information from different layers within a stratified sample using terahertz pulsed reflection imaging and spectroscopy has traditionally been resolution limited by the pulse width available. In this paper, a deconvolution algorithm is presented which circumvents this resolution limit, enabling deep sub-wavelength and sub-pulse width depth resolution. The algorithm is explained through theoretical investigation, and demonstrated by reconstructing signals reflected from boundaries in stratified materials that cannot be resolved directly from the unprocessed time-domain reflection signal.

Degradation process of lead chromate in paintings by Vincent van Gogh studied by means of spectromicroscopic methods. 3. Synthesis, characterization, and detection of different crystal forms of the chrome yellow pigment.

The painter, Vincent van Gogh, and some of his contemporaries frequently made use of the pigment chrome yellow that is known to show a tendency toward darkening. This pigment may correspond to various chemical compounds such as PbCrO(4) and PbCr(1-x)S(x)O(4), that may each be present in various crystallographic forms with different tendencies toward degradation. Investigations by X-ray diffraction (XRD), mid-Fourier Transform infrared (FTIR), and Raman instruments (benchtop and portable) and synchrotron radiation-based micro-XRD and X-ray absorption near edge structure spectroscopy performed on oil-paint models, prepared with in-house synthesized PbCrO(4) and PbCr(1-x)S(x)O(4), permitted us to characterize the spectroscopic features of the various forms.

A 100,000-year-old ochre-processing workshop at Blombos Cave, South Africa.

The conceptual ability to source, combine, and store substances that enhance technology or social practices represents a benchmark in the evolution of complex human cognition. Excavations in 2008 at Blombos Cave, South Africa, revealed a processing workshop where a liquefied ochre-rich mixture was produced and stored in two Haliotis midae (abalone) shells 100,000 years ago. Ochre, bone, charcoal, grindstones, and hammerstones form a composite part of this production toolkit.