Design and characterization of a cryogenic linear Paul ion trap for ion-neutral reaction studies.

Ultra-high vacuum conditions are ideal for the study of trapped ions. They offer an almost perturbation-free environment, where ions confined in traps can be studied for extended periods of time-facilitating precision measurements and allowing infrequent events to be observed. However, if one wishes to study processes involving molecular ions, it is important to consider the effect of blackbody radiation (BBR).

A stand-alone magnetic guide for producing tuneable radical beams.

Radicals are prevalent in gas-phase environments such as the atmosphere, combustion systems, and the interstellar medium. To understand the properties of the processes occurring in these environments, it is helpful to study radical reaction systems in isolation-thereby avoiding competing reactions from impurities. There are very few methods for generating a pure beam of gas-phase radicals, and those that do exist involve complex setups.

Off-axis parabolic mirror relay microscope for experiments with ultra-cold matter.

A new optical system is introduced for the imaging of Coulomb crystals held in a cryogenic ion trap where there are space limitations preventing the placement of an objective close to the fluorescing ions. The optical system features an off-axis parabolic (OAP) mirror relay microscope that will serve to acquire images of a lattice of fluorescing ions confined within an ultra-high-vacuum vessel operating at temperatures below 10 K. We report that the OAP mirror relay setup can resolve features smaller than the separation between neighboring ions in Coulomb crystals.

Towards state selective recombination of H under astrophysically relevant conditions.

We present studies on the thermalisation of H3+ ions in a cold He/Ar/H2 plasma at temperatures 30-70 K. We show that we are able to generate a rotationally thermalised H3+ ensemble with a population of rotational and nuclear spin states corresponding to a particular ion translational temperature. By varying the para-H2 fraction used in the experiment we are able to produce para-H3+ ions with fractional populations higher than those corresponding to thermodynamic values.

Evolutionary Algorithm Optimization of Zeeman Deceleration: Is It Worthwhile for Longer Decelerators?

In Zeeman deceleration, only a small subset of low-field-seeking particles in the incoming beam possess initial velocities and positions that place them within the phase-space acceptance of the device. In order to maximize the number of particles that are successfully decelerated to a selected final velocity, we seek to optimize the phase-space acceptance of the decelerator. Three-dimensional particle trajectory simulations are employed to investigate the potential benefits of using a covariance matrix adaptation evolutionary strategy (CMA-ES) optimization method for decelerators longer than 12 stages and for decelerating species other than H atoms.

Manipulating hydrogen atoms using permanent magnets: Characterisation of a velocity-filtering guide.

A Halbach array composed of 12 permanent magnets in a hexapole configuration is employed to deflect hydrogen atoms as they exit a Zeeman decelerator. The ability to preferentially manipulate H atoms is very useful, as there are currently very few techniques that are appropriate for purifying a beam of H atoms from precursor molecules (such as molecular hydrogen or ammonia), seed gases, and other contaminant species. The extent to which hydrogen atoms are deflected by a single Halbach array when it is tilted or shifted off the main beam axis is characterised experimentally and interpreted with the aid of a simple mathematical model.

Flowing-afterglow study of electron-ion recombination of para-H3(+) and ortho-H3(+) ions at temperatures from 60 K to 300 K.

Detailed measurements employing a combination of a cryogenic flowing afterglow with Langmuir probe (Cryo-FALP II) and a stationary afterglow with near-infrared absorption spectroscopy (SA-CRDS) show that binary electron recombination of para-H3(+) and ortho-H3(+) ions occurs with significantly different rate coefficients, (p)αbin and (o)αbin, especially at very low temperatures. The measurements cover temperatures from 60 K to 300 K. At the lowest temperature of 60 K, recombination of para-H3(+) is at least three times faster than that of ortho-H3(+) ((p)αbin=(1.

Binary recombination of H3(+) and D3(+) ions with electrons in plasma at 50-230 K.

The results of an experimental study of the H3(+) and D3(+) ions recombination with electrons in afterglow plasmas in the temperature range 50-230 K are presented. A flowing afterglow apparatus equipped with a Langmuir probe was used to measure the evolution of the electron number density in the decaying plasma. The obtained values of the binary recombination rate coefficient are αbinH3(+) = (6.

Binary and ternary recombination of D3+ ions at 80-130 K: application of laser absorption spectroscopy.

Recombination of D(3)(+) ions with electrons at low temperatures (80-130 K) was studied using spectroscopic determination of D(3)(+) ions density in afterglow plasmas. The use of cavity ring-down absorption spectroscopy enabled an in situ determination of the abundances of the ions in plasma and the translational and the rotational temperatures of the recombining ions. Two near infrared transitions at (5792.

Binary and ternary recombination of para-H3(+) and ortho-H3(+) with electrons: state selective study at 77-200 K.

Measurements in H(3)(+) afterglow plasmas with spectroscopically determined relative abundances of H(3)(+) ions in the para-nuclear and ortho-nuclear spin states provide clear evidence that at low temperatures (77-200 K) para-H(3)(+) ions recombine significantly faster with electrons than ions in the ortho state, in agreement with a recent theoretical prediction. The cavity ring-down absorption spectroscopy used here provides an in situ determination of the para/ortho abundance ratio and yields additional information on the translational and rotational temperatures of the recombining ions. The results show that H(3)(+) recombination with electrons occurs by both binary recombination and third-body (helium) assisted recombination, and that both the two-body and three-body rate coefficients depend on the nuclear spin states.