The combustion of metal fuels as energy carriers in a closed-cycle carbon-free process is a promising approach for reducing CO emissions in the energy sector. For a possible large-scale implementation, the influence of process conditions on particle properties and vice versa has to be well understood. In this study, the influence of different fuel-air equivalence ratios on particle morphology, size and degree of oxidation in an iron-air model burner is investigated by means of small- and wide-angle X-ray scattering, laser diffraction analysis and electron microscopy.
View Article and Find Full Text PDFNumerical simulations have been conducted for a novel double-concentric swirl burner, which is specifically designed for combustion of sulfur with a high power density. The burner serves as a major component of an enclosed conversion cycle, which uses elemental sulfur as a carbon-free chemical energy carrier for storing solar energy. The focus of the work is to assess operability of the burner and NO formation at fuel-lean conditions with an equivalence ratio of ϕ = 0.
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