Publications by authors named "Michal Chwalba"
Article Synopsis
- The study presents the synthesis of enantiomerically enriched 1,4-benzodioxanes with various substituents at the 2-position using ring closing metathesis with a highly efficient nitro-Grela catalyst.
- The asymmetric hydrogenation process achieved impressive enantioselectivities of up to 99:1 using an [Ir(cod)Cl]/BIDIME-dimer catalyst system.
- DFT calculations indicate that the selectivity is influenced by the protonation step and that substituent groups can affect how the substrate interacts with the catalyst, impacting the selectivity of the reaction.
