A mass budget of polybrominated diphenyl ethers (PBDEs) in San Francisco Bay is developed as a first step towards understanding the local sources and transport processes controlling PBDE fate in a highly urbanized estuary. Extensive monitoring of PBDEs in estuarine water and sediment, freshwater tributaries, air, and wastewater effluents and sludges were integrated with a mass budget model to provide a synthetic view of these emerging contaminants. The Bay inventories of BDE 47 and BDE 209 in 2006 were estimated to be 33+/-3 kg and 153+/-45 kg, respectively.
View Article and Find Full Text PDFThe use of organochlorine pesticides, including DDTs, chlordanes, and dieldrin, peaked in San Francisco Bay's watershed 30-40 years ago, yet residues of the pesticides remain high. Known as legacy pesticides for their persistence in the Bay decades after their uses ended, the compounds and their breakdown products occur at concentrations high enough to contribute to advisories against the consumption of sport fish from the Bay. Combined with other data sets, the long-term monitoring data collected by the San Francisco Estuary Regional Monitoring Program (RMP) for trace substances allow us to track recovery of the Bay from these inputs and predict its future improvement.
View Article and Find Full Text PDFMud snails (Ilyanassa obsoleta) starved for 48 h were allowed to feed on sediments in laboratory microcosms. Sediment cores sliced at 2 mm intervals were compared to snail stomach contents for per cent carbon and nitrogen, plant pigment contents and species composition of benthic diatoms. Concentrations of carbon, nitrogen, phaeopigments, phycocyanin and chlorophyll were enriched in the top 2 mm of the sediments compared to 7-10 mm depth by a factor of 2-10.
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