Temperature-dependent structural dynamics in covalent organic frameworks observed by cryogenic infrared spectroscopy.

Understanding the structural dynamics of covalent organic frameworks (COFs) in response to external temperature change is necessary for these materials' application at cryogenic temperatures. Herein, we report reversible structural dynamics observed in covalent organic frameworks as the temperature varies from 298 K to 30 K. A series of frameworks (COF-300, COF-300-amine, and COF-V) was studied using a cryogenic infrared spectroscopy system.