Characterization of artificially generated PbS aerosols and their use within a respiratory bioaccessibility test.

A new method is presented for the preparation, characterization and use of PbS (galena) nanoparticles within an in vitro bioaccessibility test representing the respiratory tract, specifically the conditions occurring in conjunction with phagocytosis by cells using artificial lysosomal fluid. Particle production through nanosecond laser ablation enables their rapid production with a relatively narrow particle size distribution, and a diameter enabling them to represent particles that can enter the alveolar region of the respiratory tract (<3 microm). The PbS nanoparticles were characterized by cascade impaction to define their particle size distribution and through the use of X-ray diffraction (XRD) and electron microprobe analysis (EMPA) to define their mineralogy and homogeneity respectively.

Migration of arsenic from old tailings ponds--a case study on the King Edward Mine, Cornwall, UK.

A methodology is presented to study the physico-chemical processes in old tailings ponds using an array of analytical-physical chemistry approaches. A case study was conducted on the sorption/desorption behaviour of arsenic in tailings pond 2406, at the King Edward Mine (KEM) in Cornwall, UK. The tailings pond was in operation from approximately 1907 to 1921.

Assessment of elemental mobility in soil using a fluidised bed approach with on-line ICP-MS analysis.

A new method has been developed to analyse the mobility of elements within soils employing counter-current flow soil contacting in a fluidised bed (FB) column. This method alleviates the problem of irreproducible peaks suffered by state-of-the-art micro-column techniques as a result of particle compaction. Reproducible extraction profiles are produced through the leaching of soil with a linear gradient of 0.