A Laser-Activated Membrane Introduction Mass Spectrometry Study of Proton Spillover Promoted Alkane Dehydrogenation.

Operando high-throughput evaluation of heterogeneous catalysts by laser-activated membrane introduction mass spectrometry (LAMIMS) elucidates the Pt loading dependence of methylcyclohexane dehydrogenation on platinized γ-alumina beads. A CO marking laser rapidly and sequentially heats catalyst beads positioned on a heat-dissipating carbon paper support that overlays a silicone membrane, separating the bead library reaction zone from a quadrupole mass analyzer. The toluene / peak varies logarithmically with Pt loading, suggesting that reactivity includes factors that are negatively correlated to Pt loading.

Paramedic tracheal intubation using the intubating laryngeal mask airway.

Objective: Tracheal intubation through the intubating laryngeal mask airway (ILMA) has been evaluated, in controlled settings, as an acceptable alternative to laryngoscopic intubation. Our observational study was designed to examine the success rate of tracheal intubation using the ILMA in the prehospital setting after mannequin-based training.

Methods: We examined all oral tracheal intubations performed by the Tasmanian Ambulance Service (TAS) from April 2005 to April 2006.

Laser-activated membrane introduction mass spectrometry for high-throughput evaluation of bulk heterogeneous catalysts.

Laser-activated membrane introduction mass spectrometry (LAMIMS), a high-throughput screening method, evaluates heterogeneous catalysts under realistic reactor conditions. It is a precise, versatile system requiring no moving parts. The catalyst array is supported on carbon paper overlaid upon a silicone rubber membrane configured in a variation of membrane introduction mass spectrometry as introduced by Cooks.