Temperature-dependent structural dynamics in covalent organic frameworks observed by cryogenic infrared spectroscopy.

Understanding the structural dynamics of covalent organic frameworks (COFs) in response to external temperature change is necessary for these materials' application at cryogenic temperatures. Herein, we report reversible structural dynamics observed in covalent organic frameworks as the temperature varies from 298 K to 30 K. A series of frameworks (COF-300, COF-300-amine, and COF-V) was studied using a cryogenic infrared spectroscopy system.

Acyclic Cucurbit[n]uril Receptors Function as Solid State Sequestrants for Organic Micropollutants.

The accumulation of organic micropollutants (OMP) in aquatic systems is a major societal problem that can be addressed by approaches including nanofiltration, flocculation, reverse osmosis and adsorptive methods using insoluble materials (e.g. activated carbon, MOFs, nanocomposites).

Practical solutions.

The experiences of black staff in the workplace are well known: inequality of treatment; lack of opportunities for advancement; exodus when they fail to gain promotion; and little representation on trust decision-making boards.