Publications by authors named "Michael B Schmithorst"

The distributions of heteroatoms within zeolite frameworks have important influences on the locations of exchangeable cations, which account for the diverse adsorption and reaction properties of zeolite catalysts. In particular for aluminosilicate zeolites, paired configurations of aluminum atoms separated by one or two tetrahedrally coordinated silicon atoms are important for charge-balancing pairs of H cations, which are active for methanol dehydration, or divalent metal cations, such as Cu, which selectively catalyze the reduction of NO, both technologically important reactions. Such paired heteroatom configurations, however, are challenging to detect and probe, due to the typically nonstoichiometric compositions and nonperiodic distributions of aluminum atoms within aluminosilicate zeolite frameworks.

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