In situ acid production by organic matter induced with trace homogeneous Fenton reagent for membrane fouling control.

The homogeneous Fenton process involves both coagulation and oxidation, but it requires added acidity, so it is rarely used to control membrane fouling. This work found that the pH of neutral simulated wastewater sharply declined to 4.1 after pre-treatment with 0.

Light-responsive and ultrapermeable two-dimensional metal-organic framework membrane for efficient ionic energy harvesting.

Nanofluidic membranes offer exceptional promise for osmotic energy conversion, but the challenge of balancing ionic selectivity and permeability persists. Here, we present a bionic nanofluidic system based on two-dimensional (2D) copper tetra-(4-carboxyphenyl) porphyrin framework (Cu-TCPP). The inherent nanoporous structure and horizontal interlayer channels endow the Cu-TCPP membrane with ultrahigh ion permeability and allow for a power density of 16.

Unlocking osmotic energy harvesting potential in challenging real-world hypersaline environments through vermiculite-based hetero-nanochannels.

Nanochannel membranes have demonstrated remarkable potential for osmotic energy harvesting; however, their efficiency in practical high-salinity systems is hindered by reduced ion selectivity. Here, we propose a dual-separation transport strategy by constructing a two-dimensional (2D) vermiculite (VMT)-based heterogeneous nanofluidic system via an eco-friendly and scalable method. The cations are initially separated and enriched in micropores of substrates during the transmembrane diffusion, followed by secondary precise sieving in ultra-thin VMT laminates with high ion flux.

Forward osmosis membrane doped with water-based zirconium fumarate MOFs to enhance dye pollutant removal and membrane antifouling performance.

Metal-organic frameworks (MOFs) can be applied to enhance the property of forward osmosis membranes. However, organic solvents can easily remain in organic synthetic metal-organic frame materials and cause membrane fouling and a decrease in membrane permeability. In this study, water-based Zr-fumarate MOFs were synthesized and doped into the membrane active layer by interfacial polymerization to provide a water-based MOF-doped thin-film composite membrane (TFC membrane).

Recent advances in thin film nanocomposite membranes containing an interlayer (TFNi): fabrication, applications, characterization and perspectives.

Polyamide (PA) reverse osmosis and nanofiltration membranes have been applied widely for desalination and wastewater reuse in the last 5-10 years. A novel thin-film nanocomposite (TFN) membrane featuring a nanomaterial interlayer (TFNi) has emerged in recent years and attracted the attention of researchers. The novel TFNi membranes are prepared from different nanomaterials and with different loading methods.

Stable Forward Osmosis Nanocomposite Membrane Doped with Sulfonated Graphene Oxide@Metal-Organic Frameworks for Heavy Metal Removal.

A sulfonated graphene oxide@metal-organic framework-modified forward osmosis nanocomposite (SGO@UiO-66-TFN) membrane was developed to improve stability and heavy metal removal performance. An in situ growth method was applied to uniformly distribute UiO-66 nanomaterial with a frame structure on SGO nanosheets to form SGO@UiO-66 composite nanomaterial. This nanomaterial was then added to a polyamide layer using interfacial polymerization.

Precisely Tunable Ion Sieving with an Al-TiCT Lamellar Membrane by Controlling Interlayer Spacing.

Two-dimensional (2D) membranes exhibit exceptional properties in molecular separation and transport, which reveals their potential use in various applications. However, ion sieving with 2D membranes is severely restrained due to intercalation-induced swelling. Here, we describe how to efficiently stabilize the lamellar architecture using Keggin Al polycations as pillars in a TiCT membrane.