Effect of Tetrapropylammonium Chloride Quaternary Ammonium Salt on Characterization, Cytotoxicity, and Antibacterial Properties of PLA/PEG Electrospun Mat.

In this study, poly(lactic acid) (PLA)-tetrapropylammonium chloride (TCL)-poly(ethylene glycol) (PEG) nonwoven networks were produced using PLA, PEG with different concentrations (3, 5, 7, and 9 wt%), and TCL. PEG is included as a plasticizer in PLA polymer, which has high biocompatibility but a brittle structure. The importance of this study is to investigate the effect of TCL salt on the characterization of PLA-PEG nanofibers.

Investigation of Superhydrophobic and Anticorrosive Epoxy Films with AlO Nanoparticles on Different Surfaces.

In this study, superhydrophobic epoxy coatings were prepared on different surfaces by utilizing hydrophobized aluminum oxide (AlO) nanoparticles. The dispersions containing epoxy and inorganic nanoparticles with different contents were coated on glass, galvanized steel, and skin-passed galvanized steel substrates by the dip coating method. The contact angles of the obtained surfaces were measured via a contact angle meter device, and the surface morphologies were analyzed by utilizing scanning electron microscopy (SEM).

Preparation of hetero-armed POSS-cored star-shaped PCL-PLA/PLA composites and effect of different diisocyanates as compatibilizer.

Eight-armed AB-type hetero-arm star-shaped PCL-PLA polymers ((PCL)-POSS-(PLA), SPLA30) with POSS core were successfully prepared via combination of the "arm-first" approach utilizing ring-opening polymerization (ROP) and click chemistry techniques. Firstly, alkyne-functional PLA and PCL polymers having arms with 30 repeating units were synthesized via ROP with utilizing propargyl alcohol as initiator and stannous octoate (Sn(Oct)) as catalyst. Then, the obtained hetero-armed star-shaped polymers were prepared by Cu(I)-catalyzed alkyne-azide cycloaddition (CuAAC) click reaction between alkyne functional polymers (1:1 PCL:PLA) and azido functional polyhedral oligomeric silsesquoxane (POSS-(N)) molecules.

Diffusion-controlled evaporation of sodium dodecyl sulfate solution drops placed on a hydrophobic substrate.

In this work, the effect of SDS anionic surfactant on the diffusion-controlled evaporation rate of aqueous solution drops placed on TEFLON-FEP substrate was investigated with 11 different SDS concentrations. Drop evaporation was monitored in a closed chamber having a constant RH of 54-57% by a video camera. The initial contact angle, θ(i) decreased from 104±2° down to 68±1° due to the adsorption of SDS both at the water-air and the solid-water interfaces.