Sub-Saharan Africa (SSA) is climatically diverse, with many biomes. Many species of invasive alien plants (IAPs) are present, with severe negative impacts that largely remain unquantified. Importation biological weed control (IBWC) has been practiced on the continent since the early 20th century, with some notable successes.
View Article and Find Full Text PDFAn interlaboratory study was conducted at 8 locations to assess the stability of pesticides on solid-phase extraction (SPE) disks after incubation at various temperatures and for various time intervals. Deionized water fortified with selected pesticides was extracted by using 2 types of SPE filtration disks (Empore C18 and Speedisk C18XF), and after extraction, the disks were incubated at 3 temperatures (25, 40, and 55 degrees C) and for 2 time intervals (4 and 14 days). Deionized water was fortified with atrazine, carbofuran, and chlorpyrifos by all participating laboratories.
View Article and Find Full Text PDFAn interlaboratory study was conducted to compare pesticide recovery from Empore C(18) and Speedisks C(18)XF solid phase extraction disks after shipping. Four pesticides were used for the comparison of the two disk extraction materials: atrazine, diazinon, metolachlor, and tebuconazole. These pesticides were chosen to provide a range of physiochemical properties.
View Article and Find Full Text PDFEnviron Toxicol Chem
November 2004
A study was conducted to determine the half-life (t1/2), degradation rate, and metabolites of metolachlor in a water-sediment system and in soil with and without switchgrass. Metolachlor degradation in a laboratory was determined in sediment from Bojac sandy loam soil incubated at 24 degrees C. The study also was conducted in a greenhouse on tilted beds filled with Bojac soil and planted with switchgrass.
View Article and Find Full Text PDFMetalaxyl is a systemic fungicide commonly used in citrus production to control Phytophthora root rot and foot rot. When applied as a drench, injury was observed on newly planted, young citrus trees. The visual injury symptoms ranged from light- to bright-yellow leaves.
View Article and Find Full Text PDFA continuation of an earlier interlaboratory comparison was conducted (1) to assess solid-phase extraction (SPE) using Empore disks to extract atrazine, bromacil, metolachlor, and chlorpyrifos from various water sources accompanied by different sample shipping and quantitative techniques and (2) to compare quantitative results of individual laboratories with results of one common laboratory. Three replicates of a composite surface water (SW) sample were fortified with the analytes along with three replicates of deionized water (DW). A nonfortified DW sample and a nonfortified SW sample were also extracted.
View Article and Find Full Text PDFAn interlaboratory study was conducted to assess the suitability of C18 solid-phase extraction disks to retain and ship different pesticides from water samples. Surface and deionized water samples were fortified with various pesticides and extracted using C18 disks. Pesticides were eluted from disks and analyzed in-house, or disks were sent to another laboratory where they were eluted and analyzed.
View Article and Find Full Text PDFThe half-lives, degradation rates, and metabolite formation patterns of atrazine (6-chloro-N2-ethyl-N4-isopropyl-1,3,5-triazine-2,4-diamine) and metolachlor [2-chloro-N-(2-ethyl-6-methylphenyl)-N-(2-methoxy-1-methylethyl) acetamide] were determined in an anaerobic wetland soil incubated at 24 degrees C for 112 d. At 0, 7, 14, 28, 42, 56, and 112 d, the soil and water were analyzed for atrazine and metolachlor, and their major metabolites. The soil oxidation-reduction potential reached -200 mV after 14 d.
View Article and Find Full Text PDFAn interlaboratory comparison was conducted in 1997 and 1998 to examine the feasibility of using C18 solid-phase extraction disks (Empore) to simultaneously determine the herbicides atrazine, bromacil, and metolachlor and the insecticide chlorpyrifos in water samples. A common fortification source and sample processing procedure were used to minimize variation in initial concentrations and operator inconsistencies. The protocol consisted of paired laboratories in different locations coordinating their activities and shipping fortified water samples (deionized or local surface water) or Empore disks on which the pesticides had been retained and then quantitating the analytes by a variety of gas chromatographic methods.
View Article and Find Full Text PDFThrough water erosion and runoff, sediment-adsorbed atrazine can undergo sedimentation and accumulation at the bottom of water bodies and become potential sources of atrazine to the water column. The purpose of this study is to determine the fate and release of atrazine ((14)C) to the water column from two simulated undisturbed submerged sediments at two temperature treatments (5 and 24 degrees C) over a 2-year period. Atrazine residue ((14)C) was released from the two sediments and was, primarily, diffusing from the sediment pore water to the water columns.
View Article and Find Full Text PDFThe effects ofp-coumaric, ferulic, chlorogenic, and vanillic acids on photosynthesis and protein synthesis by isolated leaf cells of velvetleaf (Abutilon theophrasti Medik) were investigated. Photosynthesis and protein synthesis were measured in cell suspensions by the incorporation of(14)CO2 and [(14)C]leucine, respectively. None of the tested phenolic acids except vanillic reduced photosynthesis by more than 50% at the highest concentration and 30 min of incubation.
View Article and Find Full Text PDFThe inheritance of ozone (O(3)) insensitivity in common bean (Phaseolus vulgaris L.) was evaluated using F(2) and F(3) populations under ambient conditions. This study was conducted over two growing seasons (1987, 1988) at Virginia State University, Randolph Research Farm, Petersburg, Virginia.
View Article and Find Full Text PDFAllelopathic effects of entire shoot extract, plant part extracts, and shoot residue of parthenium (Parthenium hysterophorus L.) on corn (Zea mays L.), ryegrass (Lolium multiflorum Lam.
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