Toward SERS based localized thermometry of Polymer-Supported silver and gold nanostructures.

In order to accurately account for the contribution of different plasmon mediated phenomena when developing materials for applications in photothermal therapy, photovoltaics, or photocatalysis reliable, precise, and localized temperature measurements are required. In this work we applied two surface-enhanced Raman scattering (SERS) spectroscopy based methods to measure the local temperature increase due to the thermoplasmonic effect in gold and silver nanoparticles on thin polystyrene films. The first method relies on the temperature dependence of the anti-Stokes to Stokes Raman bands intensity ratio for a label Rhodamine 6G deposited on the nanostructures.