Determination of Major and Trace Metals in Date Palm Fruit () Samples Using Flame Atomic Absorption Spectrometry and Assessment of the Associated Public Health Risks.

This study aimed to assess the concentrations of major and trace metals (Na, Ca, Fe, Zn, Ni, Mn, Cu, Cd, and Pb) in date palm fruit samples collected from diverse regions, including Afar (Ethiopia), Iraq, and Saudi Arabia, utilizing flame atomic absorption spectrometry (FAAS). The wet acid digestion method was employed for sample treatment, with optimization of the key parameters such as reagent volume ratio, oven temperature, and digestion time for analytical applications. Under the optimized parameters, average metal concentrations in date palm fruit samples ranged from 205-299, 134-320, 38.

Hypersensitive electrochemical sensor based on thermally annealed gold-silver alloy nanoporous matrices for the simultaneous determination of sulfathiazole and sulfamethoxazole residues in food samples.

In this study, we have developed a novel, hypersensitive, and ultraselective electrochemical sensor containing thermally annealed gold-silver alloy nanoporous matrices (TA-Au-Ag-ANpM) integrated with f-MWCNTs-CPE and poly(l-serine) nanocomposites for the simultaneous detection of sulfathiazole (SFT) and sulfamethoxazole (SFM) residues in honey, beef, and egg samples. TA-Au-Ag-ANpM/f-MWCNTs-CPE/poly(l-serine) was characterized using an extensive array of analytical (UV-Vis, FT-IR, XRD, SEM, and EDX), and electrochemical (EIS, CV and SWV) techniques. It exhibited outstanding performance over a wide linear range, from 4.

A cutting-edge electrochemical sensing platform for the simultaneous determination of the residues of antimicrobial drugs, rifampicin and norfloxacin, in water samples.

Background: The widespread use and abuse of antibiotics has resulted in the pollution of water sources with antibiotic residues, posing a threat to human health, the environment, and the economy. Therefore, a highly sensitive and selective method is required for their detection in water samples. Herein, advanced ultrasensitive electrochemical sensor platform was developed by integrating gold-silver alloy nanocoral clusters (Au-Ag-ANCCs) with functionalized multi-walled carbon nanotube-carbon paste electrode (f-MWCNT-CPE) and choline chloride (ChCl) nanocomposites for simultaneously determining the residues of antimicrobial drugs, rifampicin (RAMP) and norfloxacin (NFX), in water samples.

A novel electrochemical sensor for the detection of metronidazole residues in food samples.

The widespread use and misuse of antibiotics in pharmaceuticals and animal farming has resulted in their accumulation in food sources and the environment, posing significant threats to human health, the environment, and the global economy. In this study, we have developed a hypersensitive, and ultra-selective electrochemical sensor, the first of its kind, by integrating a thermally annealed gold-silver alloy nanoporous matrix (TA-Au-Ag-ANpM) with reduced graphene oxide (r-GO) and poly(glycine) at the surface of a glassy carbon electrode (GCE). This sensor aims to detect life-threatening metronidazole (MTZ) residues in food samples.

Simultaneous Determination of Mineral Nutrients and Toxic Metals in from Southern Ethiopia: A Comparative Study of Three Cultivating Areas Using MP-AES.

In this study, for the first time, the levels of thirteen micro- and macromineral nutrients in the leaves, seeds, and supportive soil of () were simultaneously determined using microwave plasma atomic emission spectroscopy (MP-AES). The samples were collected during the arid season, in 2019 from the three main growing areas in southern Ethiopia (Chano Mile Kebele, Nechisar Kebele, and Konso Special Woreda). A novel digestion method for leaf and seed samples was developed using an optimized acid mixture (2.

Electrochemical determination of zinc(II) using N-hydroxy-N,N-diphenylbenzamidine and multi-walled carbon nanotubes modified carbon paste electrode.

In this study, a new carbon paste electrode modified with a laboratory-synthesized ligand, N-hydroxy-N,N-diphenylbenzamidine (HDPBA) and multi-walled carbon nanotubes (MWCNTs) (HDPBA‒MWCNTs/CPE) has been developed. The modified electrode was applied for preconcentration and voltammetric determination of zinc ions (Zn(II)) by square wave anodic stripping voltammetry (SWASV). The preconcentration of Zn(II) on the electrode surface was performed in 0.

Development of a new electrochemical method for the determination of copper(ii) at trace levels in environmental and food samples.

This paper presents the fabrication of a new modified carbon paste electrode (CPE) with -hydroxy- , -diphenylbenzamidine (HDPBA) and functionalized multi-walled carbon nanotubes (MWCNTs) (HDPBA-MWCNTs/CPE) for highly sensitive and selective determination of Cu(ii) using the square wave anodic stripping voltammetry (SWASV) technique. The fabricated electrode was characterized using various spectroscopic techniques to study its morphological, structural, and electrochemical properties. The accumulation of Cu(ii) on the surface of HDPBA-MWCNTs/CPE was done in 0.

A Novel Carbon Paste Electrode Modified with N-Hydroxy-N,N-Diphenylbenzamidine for the Electrochemical Determination of Cadmium(II) in Environmental Samples.

The present study introduces a novel electrode for rapid, highly sensitive, and selective electrochemical sensor for cadmium(II) using 5% N-hydroxy-N,N-diphenylbenzamidine (HDPBA) modified carbon paste electrode (CPE) (HDPBA‒CPE). Surface characterizations and structural analysis of the proposed HDPBA‒CPE were performed using several analytical techniques. The voltammetric measurements of Cd(II) were conducted by cyclic voltammetry (CV) and square wave anodic stripping voltammetry (SWASV).

Sensitive and selective determination of vitamin B2 in non-alcoholic beverage and milk samples at poly (glutamic acid)/zinc oxide nanoparticles modified carbon paste electrode.

Background: The deficiency of vitamin B2 can lead to many health problems. Therefore, it is necessary to develop a sensitive, selective and fast method for the determination of vitamin B2 in food samples. In this work, a sensitive, selective and low-cost electrochemical sensor was developed using poly (glutamic acid) and Zinc oxide nanoparticles (ZnO NPs) for vitamin B2 in non-alcoholic beverage and milk samples.

Electrochemical application of cobalt nanoparticles-polypyrrole composite modified electrode for the determination of phoxim.

In this study, cobalt nanoparticles (CoNPs) were synthesized and cobalt nanoparticles modified glassy carbon electrode (CoNPs/GCE) was prepared by drop coating the nanoparticles on glassy carbon electrode. After preparing polypyrrole modified glassy carbon electrode (PPy/GCE) using electropolymerization of pyrrole in LiClO solution, cobalt nanoparticles-polypyrrole composite modified glassy carbon electrode (CoNPs/PPy/GCE) was fabricated by drop coating the CoNPs on the PPy/GCE. Different characterization techniques such as scanning electron microscopy, transmission electron microscopy, energy dispersive spectroscopy, FTIR spectroscopy, electrochemical impedance spectroscopy and cyclic voltammetry were used to study the morphological structure and electrochemical behavior of the sensors.

Voltammetric determination of uric acid using multiwall carbon nanotubes coated-poly(4-amino-3-hydroxy naphthalene sulfonic acid) modified glassy carbon electrode.

In this study, an electrochemical sensor based multiwalled carbon nanotubes (MWCNTs)-poly (4-amino-3-hydroxy naphthalene sulfonic acid) modified glassy carbon electrode (MWCNTs/poly (AHNSA)/GCE) was developed for the determination of uric acid (UA). The composite electrode was prepared first by electropolymerization of the monomer (AHNSA) on GCE using cyclic voltammetry within the potential range of -0.8 V to +2.

Simultaneous determination of caffeine and paracetamol by square wave voltammetry at poly(4-amino-3-hydroxynaphthalene sulfonic acid)-modified glassy carbon electrode.

Poly(4-amino-3-hydroxynaphthalene sulfonic acid)-modified glassy carbon electrode (poly(AHNSA)/GCE) was prepared for simultaneous determination of caffeine and paracetamol using square-wave voltammetry. The method was used to study the effects of pH and scan rate on the voltammetric response of caffeine and paracetamol. Linear calibration curves in the range of 10-125μM were obtained for both caffeine and paracetamol in acetate buffer solution of pH 4.

Electrochemical Characterization and Determination of Phenol and Chlorophenols by Voltammetry at Single Wall Carbon Nanotube/Poly(3,4-ethylenedioxythiophene) Modified Screen Printed Carbon Electrode.

Screen printed carbon electrode (SPCE) has been modified with single wall carbon nanotube/poly(3,4-ethylenedioxythiophene) (SWCNT/PEDOT) composites for the determination of phenol and chlorophenols (phenol, 4-chlorophenol, 2,4-dichlorophenol, and 2,4,6-trichlorophenol). The effect of the modifiers on the electrode characteristics was evaluated and the responses were optimized for the voltammetric determination of phenol and chlorophenols. The parameters affecting the responses such as pH, scan rate, and stability were studied.

Stripping voltammetric determination of pyridine-2-aldoxime methochloride at the iron(III) doped zeolite modified glassy carbon electrode.

An iron(III) doped zeolite modified glassy carbon electrode was constructed for the determination of pyridine-2-aldoxime methochloride. X-ray diffraction and chemical analysis were utilized to determine the optimum pH and chemical content for doping zeolite. Cyclic voltammetry was used to characterize the modified electrode and study the kinetics of the acid treated and untreated modified electrode.

Polymer-modified glassy carbon electrode for the electrochemical detection of quinine in human urine and pharmaceutical formulations.

Glassy carbon electrode was modified by electropolymerization of 4-amino-3-hydroxynaphthalene sulfonic acid. Cyclic voltammetric study of quinine showed higher current response at the modified electrode compared to the bare and activated glassy carbon electrodes in pH 7.0 phosphate buffer solution.

Simultaneous determination of N-acetyl-p-aminophenol and p-aminophenol with poly(3,4-ethylenedioxythiophene) modified glassy carbon electrode.

A sensitive and selective method was developed for the determination of N-acetyl-p-aminophenol (APAP) and p-aminophenol (PAP) using poly(3,4-ethylenedioxythiophene) (PEDOT)-modified glassy carbon electrode (GCE). Cyclic voltammetry and differential pulse voltammetry were used to investigate the electrochemical reaction of APAP and PAP at the modified electrode. Both APAP and PAP showed quasireversible redox reactions with formal potentials of 367 mV and 101 mV (vs.

Indirect voltammetric determination of caffeine content in coffee using 1,4-benzoquinone modified carbon paste electrode.

In this paper a simple and highly sensitive electroanalytical method for the determination of caffeine content using 1,4-benzoquinone modified carbon paste electrode is presented. The method is based on suppression of 1,4-benzoquinone peak current on addition of caffeine. Square-wave and cyclic voltammetric techniques were utilised for the investigation.