Capillary zone electrophoresis for U(VI) and short chain carboxylic acid sorption studies on silica and rutile.

Capillary zone electrophoresis was used to study the uranyl and short chain carboxylic acid sorption on silica and rutile. The separation and the simultaneous determination (in a single run) of a number of short chain carboxylic acids (oxalic, formic, acetic and propionic) and U(VI) with direct UV detection is developed for the analysis of solutions after the sorption experiments. The reverse polarity mode is used (the injection is performed at the negative end).

Interaction between U(VI) and SrTiO3 surfaces versus temperature.

The purpose of this work is the study of the interaction mechanisms between U(VI) ions and SrTiO(3) surfaces as a function of pH and temperature (25, 50, 75 and 90 degrees C) by coupling thermodynamic and spectroscopic approaches. First, the reactivity towards U(VI) for both surface sites of the strontium titanate ([triple bond]Ti-O and [triple bond]Sr-O) has been investigated as a function of the temperature. The N(2)-BET specific area was measured: 2.

Comparison between batch and column experiments to determine the surface charge properties of rutile TiO2 powder.

This paper reports a comparative study of three methods for determining the surface charge and acid-base behavior of a TiO(2) rutile material. Electrophoretic mobility measurements were performed using two different batch protocols: (i) a "static" mode that consisted of immersing the rutile powder in aqueous solutions of given pH's and ionic strengths for 10 h, and (ii) a "dynamic" mode that consisted of using an automatic titrator to continuously adjust the solution pH with a contact time of 15 min. The same apparatus (a Nanosizer from Malvern) was used to measure the zeta potential of the particles in both methods.

Surface complexation modeling of uranium(VI) sorbed onto zirconium oxophosphate versus temperature: thermodynamic and structural approaches.

This work presents an investigation of the interaction mechanisms between uranyl ions and a solid phosphate, the zirconium oxophosphate: Zr2O(PO4)2. Both thermodynamic and structural points of view are developed. Indeed, prior to any simulation of the retention data, it is necessary to precisely characterize the system under study in order to gain information at a molecular scale.

Temperature effects on the surface acidity properties of zirconium diphosphate.

As part of the temperature effects study on the sorption of metallic cations onto zirconium diphosphate, we have first investigated the intrinsic surface properties of this synthetic compound for different temperatures (25, 50, 75 and 90 degrees C). A physico-chemical study (IR, XRD) assessed its purity, and the measured N(2)-BET specific area was 13.4+/-0.