Regulating ion transport is a prevailing strategy to suppress lithium dendrite growth, in which the distribution of ion regulatory sites plays an important role. Here a hyperbranched polyamidoamine (HBPA) grafted polyethylene (PE) composite separator (HBPA--PE) is reported. The densely and uniformly distributed positive -NH and negative -CHNO- groups efficiently restrict the anion migration and promote Li transport at the surface of the lithium metal anode.
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