Graphene oxide (GO)-based membranes have demonstrated great potential in water treatment. However, microdefects in the framework of GO membranes induced by the imperfect stacking of GO nanosheets undermine their size-sieving ability and structural stability in aqueous systems. This study proposes a targeted growth approach by growing zeolitic imidazolate framework-8 (ZIF-8) nanocrystals precisely to patch microdefects as well as to cross-link the porous graphene oxide (PGO) flakes coated on the outer surface of the hollow fiber (HF) alumina substrate (named the hybrid PGO/ZIF-8 membrane).
View Article and Find Full Text PDFMetal‒organic frameworks (MOFs) are nanoporous crystalline materials with enormous potential for further development into a new class of high-performance membranes. However, the preparation of defect-free and water-stable MOF membranes with high permselectivity and good structural integrity remains a challenge. Herein, we demonstrate a dual-source seeding (DS) approach to produce high-performance, water-stable MOF-303 membranes with hollow fiber (HF) geometry and preferentially tailored crystallographic orientation.
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