New kinds of crystalline waste forms with improved structural stability are desirable for actinide immobilization. In this work, using a molten salt method, two uranium(IV) germanate compounds, namely, KUGeO () and KUGeO (), were synthesized, whose compositions consisted of trimeric and dimeric units of germanate, as well as tetravalent uranium, as proved by bond valence calculation and X-ray absorption spectra. Radiation stability assessment is further performed by γ-irradiation to assess the potential of as-synthesized uranium germanate compounds as nuclear waste forms.
View Article and Find Full Text PDFSoc Cogn Affect Neurosci
November 2024
Angew Chem Int Ed Engl
October 2024
Fiber zinc-air batteries are explored as promising power systems for wearable and portable electronic devices due to their intrinsic safety and the use of ambient oxygen as cathode material. However, challenges such as limited zinc anode reversibility and sluggish cathode reaction kinetics result in poor cycling stability and low energy efficiency. To address these challenges, we design a polydopamine-based all-in-one gel electrolyte (PAGE) that simultaneously regulates the reversibility of zinc anodes and the kinetics of air cathodes through polydopamine interfacial and redox chemistry, respectively.
View Article and Find Full Text PDFAll-solid-state lithium-sulfur batteries (ASSLSBs) have attracted intense interest due to their high theoretical energy density and intrinsic safety. However, constructing durable lithium (Li) metal anodes with high cycling efficiency in ASSLSBs remains challenging due to poor interface stability. Here, a compositionally stable, self-lithiated tin (Sn)-carbon (C) composite interlayer (LSCI) between Li anode and solid-state electrolyte (SSE), capable of homogenizing Li-ion transport across the interlayer, mitigating decomposition of SSE, and enhancing electrochemical/structural stability of interface, is developed for ASSLSBs.
View Article and Find Full Text PDFRecently, water resources have become scarce due to the growing global population and human impact on the environment, coupled with the effects of climate change. For solving the problem of global freshwater shortage and increasing the value of discarded polyphenylene sulfide (PPS) filter bags, in this study, balsa wood was used as the base of a photothermal solar evaporator, chitosan solution was used as the binder, and the main photothermal conversion materials used were polyphenylene sulfide (CP) carbide and copper sulfide. In order to create synergistic photothermal conversion materials, freeze-drying and precipitation were used to deposit the photothermal conversion materials on top of the balsa wood.
View Article and Find Full Text PDFReplacement of liquid electrolytes with polymer gel electrolytes is recognized as a general and effective way of solving safety problems and achieving high flexibility in wearable batteries. However, the poor interface between polymer gel electrolyte and electrode, caused by insufficient wetting, produces much poorer electrochemical properties, especially during the deformation of the battery. Here we report a strategy for designing channel structures in electrodes to incorporate polymer gel electrolytes and to form intimate and stable interfaces for high-performance wearable batteries.
View Article and Find Full Text PDFTransmission and processing of sensory information in the visual system takes time. For motion perception, our brain can overcome this intrinsic neural delay through extrapolation mechanisms and accurately predict the current position of a continuously moving object. But how does the system behave when the motion abruptly changes and the prediction becomes wrong? Here we address this question by studying the perceived position of a moving object with various abrupt motion changes by human observers.
View Article and Find Full Text PDFIntroduction: Changes in vision that occur in normal healthy aging can be seen in fundamental measures of monocular vision. However, the nature of the changes in binocular vision with age remain unclear.
Methods: A total of 28 older (53-66 years) and 28 younger adults (20-31 years) were enrolled in this study.
Calcium-oxygen (Ca-O) batteries can theoretically afford high capacity by the reduction of O to calcium oxide compounds (CaO) at low cost. Yet, a rechargeable Ca-O battery that operates at room temperature has not been achieved because the CaO/O chemistry typically involves inert discharge products and few electrolytes can accommodate both a highly reductive Ca metal anode and O. Here we report a Ca-O battery that is rechargeable for 700 cycles at room temperature.
View Article and Find Full Text PDFRechargeable calcium (Ca) metal batteries are promising candidates for sustainable energy storage due to the abundance of Ca in Earth's crust and the advantageous theoretical capacity and voltage of these batteries. However, the development of practical Ca metal batteries has been severely hampered by the current cathode chemistries, which limit the available energy and power densities, as well as their insufficient capacity retention and low-temperature capability. Here, we describe the rechargeable Ca/Cl battery based on a reversible cathode redox reaction between CaCl and Cl, which is enabled by the use of lithium difluoro(oxalate)borate as a key electrolyte mediator to facilitate the dissociation and distribution of Cl-based species and Ca.
View Article and Find Full Text PDFProc Natl Acad Sci U S A
January 2024
Rechargeable lithium (Li) metal batteries face challenges in achieving stable cycling due to the instability of the solid electrolyte interphase (SEI). The Li-ion solvation structure and its desolvation process are crucial for the formation of a stable SEI on Li metal anodes and improving Li plating/stripping kinetics. This research introduces an interfacial desolvation coating technique to actively modulate the Li-ion solvation structure at the Li metal interface and regulate the participation of the electrolyte solvent in SEI formation.
View Article and Find Full Text PDFACS Appl Mater Interfaces
August 2023
Rechargeable lithium metal batteries (LMBs) using high-voltage cathodes have been attractive in delivering high-energy density, but it is still challenging to reach excellent cycling performance for practical applications due to the notorious reactivity of metallic lithium as well as the unstable nature of the cathode. Here, we demonstrate a formulated carbonated-based electrolyte with LiPF that supports the most commercial aggressive and high-voltage cathode with the combination of cosolvent, diluent, and additives to address the issue in LMBs by providing a stable interface/interphase on both the anode and cathode. The electrolyte's solvation structure is adjusted to reduce free carbonate solvents in the decomposition and contribution to the solid-electrolyte interphase (SEI) formation.
View Article and Find Full Text PDFAngew Chem Int Ed Engl
September 2023
Chlorine (Cl)-based batteries such as Li/Cl batteries are recognized as promising candidates for energy storage with low cost and high performance. However, the current use of Li metal anodes in Cl-based batteries has raised serious concerns regarding safety, cost, and production complexity. More importantly, the well-documented parasitic reactions between Li metal and Cl-based electrolytes require a large excess of Li metal, which inevitably sacrifices the electrochemical performance of the full cell.
View Article and Find Full Text PDFMoisture harvesters with favourable attributes such as easy synthetic availability and good processability as alternatives for atmospheric moisture harvesting (AWH) are desirable. This study reports a novel nonporous anionic coordination polymer (CP) of uranyl squarate with methyl viologen (MV ) as charge balancing ions (named U-Squ-CP) which displays intriguing sequential water sorption/desorption behavior as the relative humidity (RH) changes gradually. The evaluation of AWH performance of U-Squ-CP shows that it can absorb water vapor under air atmosphere at a low RH of 20 % typical of the levels found in most dry regions of the world, and have good cycling durability, thus demonstrating the capability as a potential moisture harvester for AWH.
View Article and Find Full Text PDFEnviron Sci Pollut Res Int
July 2023
TiO is a promising photocatalyst used in practical environmental remediation. TiO photocatalysts are usually implemented in two forms: suspended powder and immobilized thin films. A simple technique for fabricating TiO thin film photocatalyst was developed in this work.
View Article and Find Full Text PDFIt is an ongoing goal to achieve the effective regulation of the thermal expansion properties of materials. In this work, we propose a method for incorporating host-guest complexation into a framework structure and construct a flexible cucurbit[8]uril uranyl-organic polythreading framework, U(bcbpy)(CB8). U(bcbpy)(CB8) can undergo huge negative thermal expansion (NTE) and has a large volumetric coefficient of -962.
View Article and Find Full Text PDFTowards the difficulties of traditional processing technology in loading high-concentration functional fillers to realize the target electromagnetic interference shielding (EMI SE) performance, and constructing the arbitrary-designated architectures for serving advanced electronics, this work innovatively formulated a functional multi-walled carbon nanotubes@cellulose nanofibers (MWCNT@OCNF) ink for direct ink writing (DIW) 3D printing, which not only possessed high freedom on the proportion of functional particles, but also imparted to the ideal rheological performance for 3D printing. Based on the pre-programmed printing trajectories, a series of porous scaffolds featuring exceptional functionalities were architected. Particularly for the electromagnetic waves (EMWs) shielding behaviors, the optimized one with "full-mismatched" architecture posed the ultralight structure (0.
View Article and Find Full Text PDFAngew Chem Int Ed Engl
July 2023
Anode-free lithium (Li) metal batteries are desirable candidates in pursuit of high-energy-density batteries. However, their poor cycling performances originated from the unsatisfactory reversibility of Li plating/stripping remains a grand challenge. Here we show a facile and scalable approach to produce high-performing anode-free Li metal batteries using a bioinspired and ultrathin (250 nm) interphase layer comprised of triethylamine germanate.
View Article and Find Full Text PDFAngew Chem Int Ed Engl
June 2023
Fiber lithium-ion batteries represent a promising power strategy for the rising wearable electronics. However, most fiber current collectors are solid with vastly increased weights of inactive materials and sluggish charge transport, thus resulting in low energy densities which have hindered the development of fiber lithium-ion batteries in the past decade. Here, a braided fiber current collector with multiple channels was prepared by multi-axial winding method to not only increase the mass fraction of active materials, but also to promote ion transport along fiber electrodes.
View Article and Find Full Text PDFLithium-sulfur all-solid-state batteries using inorganic solid-state electrolytes are considered promising electrochemical energy storage technologies. However, developing positive electrodes with high sulfur content, adequate sulfur utilization, and high mass loading is challenging. Here, to address these concerns, we propose using a liquid-phase-synthesized LiPS-2LiBH glass-ceramic solid electrolyte with a low density (1.
View Article and Find Full Text PDFPurpose: Noninvasive coronary CT angiography (CCTA) was used to retrospectively analyze the characteristics of coronary artery disease (CAD) in patients with thoracic tumors and the impact of the results on clinical surgery decision-making, thus increasing the understanding of perioperative cardiac risk evaluation.
Method: A total of 779 patients (age 68.6 ± 6.
Correction for 'Virtual microwells for digital microfluidic reagent dispensing and cell culture' by Irwin A. Eydelnant , , 2012, , 750-757, https://doi.org/10.
View Article and Find Full Text PDFBackground: Idiopathic congenital nystagmus (ICN) is an inherited disorder characterized by uncontrollable binocular conjugating oscillation. X-linked idiopathic congenital nystagmus is one of the most prevalent types of ICN. Elucidation of the genetic mechanisms involved in ICN will enhance our understanding of its molecular etiology.
View Article and Find Full Text PDFFlexible batteries based on gel electrolytes with high safety are promising power solutions for wearable electronics but suffer from vulnerable electrode-electrolyte interfaces especially upon complex deformations, leading to irreversible capacity loss or even battery collapse. Here, a supramolecular sol-gel transition electrolyte (SGTE) that can dynamically accommodate deformations and repair electrode-electrolyte interfaces through its controllable rewetting at low temperatures is designed. Mediated by the micellization of polypropylene oxide blocks in Pluronic and host-guest interactions between α-cyclodextrin (α-CD) and polyethylene oxide blocks, the high ionic conductivity and compatibility with various salts of SGTE afford resettable electrode-electrolyte interfaces and thus constructions of a series of highly durable, flexible aqueous zinc batteries.
View Article and Find Full Text PDF