Ecotoxicological Effects of Microplastics Combined With Antibiotics in the Aquatic Environment: Recent Developments and Prospects.

Both microplastics and antibiotics are commonly found contaminants in aquatic ecosystems. Microplastics have the ability to absorb antibiotic pollutants in water, but the specific adsorption behavior and mechanism are not fully understood, particularly in relation to the impact of microplastics on toxicity in aquatic environments. We review the interaction, mechanism, and transport of microplastics and antibiotics in water environments, with a focus on the main physical characteristics and environmental factors affecting adsorption behavior in water.

Advancements in Polymer-Assisted Layer-by-Layer Fabrication of Wearable Sensors for Health Monitoring.

Recent advancements in polymer-assisted layer-by-layer (LbL) fabrication have revolutionized the development of wearable sensors for health monitoring. LbL self-assembly has emerged as a powerful and versatile technique for creating conformal, flexible, and multi-functional films on various substrates, making it particularly suitable for fabricating wearable sensors. The incorporation of polymers, both natural and synthetic, has played a crucial role in enhancing the performance, stability, and biocompatibility of these sensors.

Current development and future challenges in microplastic detection techniques: A bibliometrics-based analysis and review.

Microplastics have been considered a new type of pollutant in the marine environment and have attracted widespread attention worldwide in recent years. Plastic particles with particle size less than 5 mm are usually defined as microplastics. Because of their similar size to plankton, marine organisms easily ingest microplastics and can threaten higher organisms and even human health through the food chain.

Graphdiyne applications in sensors: A bibliometric analysis and literature review.

Graphdiyne is a two-dimensional carbon nanomaterial synthesized artificially in 2010. Its outstanding performance is considered to have great potential in different fields. This article summarizes the work of graphdiyne in the sensing field by literature summary and bibliometrics analysis.

Relationship between graphene and pedosphere: A scientometric analysis.

The mass production and application of graphene have gradually expanded from academic research to industrial applications, which will inevitably lead to graphene entering the soil actively and passively. Therefore, the relationship between graphene and the pedosphere has attracted a lot of attention in the last decade. The most important question is whether graphene will harm soil health.

A review of organophosphorus flame retardants (OPFRs): occurrence, bioaccumulation, toxicity, and organism exposure.

Organophosphorus flame retardants (OPFRs) are increasingly being applied as flame retardants due to their unique properties. OPFRs are commonly detected in various environmental matrices, and organisms are extensively exposed to them. Considering the adverse effects of OPFRs, many researchers have devoted their attention to environmental risk assessments.

ZnO nanoparticles: recent advances in ecotoxicity and risk assessment.

The widespread application of zinc oxide nanoparticles (nano-ZnO) has received increasing attention because of their potential risks to human health and the environment. This review summarizes the relationship between the toxic effects and physicochemical properties of nano-ZnO and the underlying toxicity mechanisms of nano-ZnO. This study presents the possible human health hazards posed by nano-ZnO exposure and the biotoxicity to bacteria, algae, higher plants, aquatic animals, terrestrial invertebrates and vertebrates and .

A review on silver nanoparticles-induced ecotoxicity and the underlying toxicity mechanisms.

Silver nanoparticles (Ag-NPs) are increasingly being applied in many consumer products due to their unique properties. Widespread use of Ag-NPs leads to an increasing human exposure to Ag-NPs in many different pathways. This review summarized the toxicity mechanisms of Ag-NPs based on various environmentally relevant test species, such as bacteria, cells, plants, aquatic animals and mammals, in both in vitro and in vivo experiments.

Parental transfer of perfluorooctane sulfonate and ZnO nanoparticles chronic co-exposure and inhibition of growth in F1 offspring.

Perfluorooctane sulfonate (PFOS) and ZnO nanoparticles (Nano-ZnO) are two kinds of environmental contaminants that have been frequently detected in natural waters. The potential joint toxicity of PFOS and nano-ZnO remains to be fully elucidated. The objective of this study was to evaluate co-exposure effects of PFOS and nano-ZnO on growth in initial generation (F0) zebrafish after chronic exposure and to examine possible parental transfer of PFOS and nano-ZnO transgenerational effects on the growth of first generation (F1) larvae.

Biomagnification and enantiomeric profiles of organochlorine pesticides in food web components from Zhoushan Fishing Ground, China.

Trophodynamics and chiral signatures of organochlorine pesticides (OCPs), including dichlorodiphenyltrichloroethanes (DDTs), hexachlorocyclohexanes (HCHs), and chlordanes in a food web from Zhoushan Fishing Ground, China, were studied. Residues of OCPs in all teleost fishes were within food safety levels. Strong positive correlations were found between trophic levels (TLs) and wet weight concentrations of target chemicals, with trophic magnification factors (TMFs) from 4.

Neurological responses of embryo-larval zebrafish to short-term sediment exposure to decabromodiphenylethane.

Decabromodiphenylethane (DBDPE) has been widely used as an alternative flame retardant due to the restriction or phase-out of traditional polybrominated diphenyl ethers (PBDEs), and is of increasing concern regarding its ubiquity, persistence, and potential adverse effects. In the present study, the toxicological effects of DBDPE were evaluated using zebrafish as an in vivo model. Upon being exposed to DBDPE-polluted sediments for a short term, it was found that the mortality and malformation of zebrafish (including edema, bent notochord, and bent tail) were not affected even at the highest concentration tested (1000.

Early life exposure of zebrafish (Danio rerio) to synthetic pyrethroids and their metabolites: a comparison of phenotypic and behavioral indicators and gene expression involved in the HPT axis and innate immune system.

Ecotoxicological studies have revealed the association between synthetic pyrethroid (SP) exposure and aquatic toxicity in fish; however, research on the toxic effects of SP metabolites is still limited. In this study, the toxicity of two SPs (permethrin (PM) and β-cypermethrin (β-CP)) and their three metabolites (3-phenoxybenzoic alcohol (PBCOH), 3-phenoxybenzaldehyde (PBCHO), and 3-phenoxybenzoic acid (PBCOOH)) towards zebrafish embryos and larvae was evaluated. Both SPs and their metabolites exhibited significant developmental toxicities, caused abnormal vascular development, and changed locomotor activities in larvae.

Distribution and enantiomeric profiles of organochlorine pesticides in surface sediments from the Bering Sea, Chukchi Sea and adjacent Arctic areas.

The spatial distribution, compositional profiles, and enantiomer fractions (EFs) of organochlorine pesticides (OCPs), including hexachlorocyclohexanes (HCHs), dichlorodiphenyltrichloroethanes (DDTs), and chlordanes (CHLs), in the surface sediments in the Bering Sea, Chukchi Sea and adjacent areas were investigated. The total concentrations of DDTs, HCHs and CHLs varied from 0.64 to 3.

Finite Dilution Inverse Gas Chromatography as a Versatile Tool To Determine the Surface Properties of Biofillers for Plastic Composite Applications.

An improved understanding of a filler’s surface properties is important for determining the most effective polymer reinforcement fillers. In this work, the surface characteristics of two biofillers, namely, clam shell modified by hydrochloric acid (AMF) and furfural (FMF), were investigated using inverse gas chromatography (IGC). The IGC results showed that the dispersive surface energy (γ(S)(D)) contributed the major part to the total surface energy for the biofillers.

Residues and chiral signatures of organochlorine pesticides in mollusks from the coastal regions of the Yangtze River Delta: source and health risk implication.

The residues and enantiomeric fractions of organochlorine pesticides (OCPs) were measured in 11 mollusk species collected from the coastal areas along the Yangtze River Delta to evaluate the status, potential sources, and health risks of pollution in these areas. The concentrations of DDTs, HCHs, and chlordanes ranged from 6.22 to 398.

Immunotoxicity of pyrethroid metabolites in an in vitro model.

Risk assessment of man-made chemicals such as pesticides are mainly focused on parent compounds, and relatively little is known about their metabolites, especially with regard to target organ damages such as immunotoxicity. In the present study, the immunotoxicity of five synthetic pyrethroids (SPs) and three common metabolites was evaluated using an in vitro model by 3-(4,5-dimethylthiazol-2-yl)-2,5-diphenyltetrazolium bromide (MTT) assay, cytoflow, and enzyme-linked immunosorbent assay (ELISA). Cell viability and apoptosis assays showed that both SPs and their metabolites possessed cytotoxicity to the monocytic cells.

Dual enantioselective effect of the insecticide bifenthrin on locomotor behavior and development in embryonic-larval zebrafish.

Bifenthrin (BF) is a synthetic pyrethroid that targets the nervous system of insects and may have adverse effects on the behavior and development of nontarget organisms. However, no reports have been issued on the effects of different enantiomers on locomotor behavior for synthetic pyrethroids (SPs) in zebrafish, and whether locomotor activity is associated with the developmental toxicities remains unclear. In this study, enantioselectivity of BF (1S and 1R) on the acute locomotor activity and developmental toxicities of embryonic-larval zebrafish were first evaluated.

Estrogenic activities of two synthetic pyrethroids and their metabolites.

Synthetic pyrethroids (SPs) are among the most common pesticides in current use, and so far, several SPs have been assessed for their potential estrogenicities by various methods. Previous studies have shown that the estrogenicities partly come from their metabolites. Although considerable information is available with respect to the metabolism and environmental degradation of SPs, little is known about the estrogenicities of the metabolites.

Developmental toxicity of bifenthrin in embryo-larval stages of zebrafish.

Bifenthrin (BF) is widely used as a miticide in orchards, nurseries and homes due to its great photostability and insecticidal activity. Recently, extensive research has been conducted on the toxicity of BF in in vitro and in vivo assays. However, no data is so far available regarding the developmental toxicity of BF to fish in early life stages.

Enantioselective phytoeffects of chiral pesticides.

Chirality exists extensively in nature. Synthetic chiral plant growth regulators and other pesticides usually behave enantioselectively in phyto-biochemical processes. Chiral plant growth regulators regulate the physiological processes of plants enantioselectively, and chiral pesticides cause enantioselective toxicities or ecotoxicities to plants.

Separation and toxicity of salithion enantiomers.

Enantioseletive toxicities of chiral pesticides have become an environmental concern recently. In this study, we evaluated the enantiomeric separation of salithion on a suite of commercial chiral columns and assessed the toxicity of enantiomers toward butyrylcholinesterase and Daphnia magna. Satisfactory separations of salithion enantiomers could be achieved on all tested columns, that is, Chiralcel OD, Chiralcel OJ, and Chiralpak AD column.

Relation of diclofop-methyl toxicity and degradation in algae cultures.

Information on the effects of pesticide degradation on aquatic organisms is needed to properly evaluate the ecotoxicity arising from the use of pesticides and for aquatic risk assessment. This work evaluated the toxicity of diclofop-methyl (DM) and its two major metabolites, diclofop (DC) and 4-(2,4-dichlorophenoxy)-phenol (DP), to three freshwater microalgae, Chlorella pyrenoidosa, Chlorella vulgaris, and Scenedesmus obliquus. The degradation of DM in the algal suspensions was determined.