Transition metal selenides (TMSe) are promising oxygen evolution reaction (OER) electrocatalysts but act as precursors rather than the actual active phase, transforming into amorphous oxyhydroxides during OER. This transformation, along with the formation of selenium oxyanions and unstable heterointerfaces, complicates the structure-activity relationship and reduces stability. This work introduces novel "layered-hierarchical dual lattice strain engineering" to inhibit the surface reconstruction of NiSe by modulating both the nickel foam (NF) substrate with MoN nanosheets (NM) and the NiSe nanorods-nanosheets catalytic layer (NiSe-NiSe-NiO, NSN) with ultrafast interfacial bimetallic amorphous NiFeOOH coating, achieving the optimized NM/NSN/NiFeOOH configuration.
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