Sustainable Pb(II) Removal and Recovery from Wastewater Using a Bioinspired Metal-Phenolic Hybrid Membrane with Efficient Regeneration.

High-performance adsorbents often require efficient selectivity in wastewater, recoverability, and ease of multiple regeneration cycles, but achieving this remains a significant challenge. We report a new strategy for the efficient removal of lead (Pb(II)) from contaminated water streams using an innovative tannic acid (TA)-Fe(III)-based metal-phenolic network (MPN) hybrid membrane (MPN-PAM). This novel membrane exploits the tunable pH-sensitive coordination structure of the MPN to achieve selective removal and recovery of Pb(II) while enabling efficient membrane regeneration by filtration.

Efficient Removal and Recovery of Ag from Wastewater Using Charged Polystyrene-Polydopamine Nanocoatings and Their Sustainable Catalytic Application in 4-Nitrophenol Reduction.

This study addresses the long-standing challenges of removing and recovering trace silver (Ag) ions from wastewater while promoting their sustainable catalysis utilization. We innovatively developed a composite material by combining charged sulfonated polystyrene (PS) with a PDA coating. This composite serves a dual purpose: effectively removing and recovering trace Ag from wastewater and enabling reused Ag for sustainable applications, particularly in the catalytic reduction of 4-nitrophenol (4-NP) to 4-aminophenol (4-AP).

Ultrasensitive Glutathione-Mediated Facile Split-Type Electrochemiluminescence Nanoswitch Sensing Platform.

Seeking for an advanced electrochemiluminescence (ECL) platform is still an active and continuous theme in the ECL-sensing realm. This work outlines a femtomolar-level and highly selective glutathione (GSH) and adenosine triphosphate (ATP) ECL assay strategy using a facile split-type gold nanocluster (AuNC) probe-based ECL platform. The system utilizes GSH as an efficient etching agent to turn on the MnO/AuNC-based ECL nanoswitch platform.

Facile electrochemiluminescence sensing platform based on high-quantum-yield gold nanocluster probe for ultrasensitive glutathione detection.

This report outlines a highly sensitive and facile electrochemiluminescence (ECL) sensing platform based on a novel high-quantum-yield Au-nanocluster (AuNC) probe for glutathione (GSH) detection. Owing to the prominent quenching effect of GSH on the ECL of the AuNCs, the proposed ECL nanosensor showed a wide response to GSH in the ranges of 1.0 × 10-1.

Valence States Effect on Electrogenerated Chemiluminescence of Gold Nanocluster.

This work elucidated the valence states effect on the electrogenerated chemiluminescence (ECL) performance of gold nanocluster (AuNC). The N-acetyl-l-cysteine-AuNCs (NAC-AuNCs) and the electrochemical reduction method for reducing the AuNCs were first employed to this study. Results demonstrate that the electrochemical reduction degree of the AuNCs depended on the reduction potential, and the enhancement of the ECL signals was positively correlated with the reduction degree of AuNCs, which indicated that the valence state of Au plays a vital role in the ECL performance of AuNCs.