Recent Advances in Engineering Fe-N-C Catalysts for Oxygen Electrocatalysis in Zn-Air Batteries.

Fe-N-C single-atom catalysts (SACs) have emerged as one of the most promising candidates for oxygen electrocatalysis due to their maximized atom utilization efficiency, high intrinsic activity, and strong metal-support interaction. Significant progress has been made in engineering Fe-N-C SACs for oxygen electrocatalysis in Zn-air batteries (ZABs). This review provides a comprehensive overview of the recent advancements in Fe-N-C SACs, with a special focus on effective engineering strategies, their performance in oxygen electrocatalysis, and their potential applications in ZABs.

Non-noble metal single-atoms for oxygen electrocatalysis in rechargeable zinc-air batteries: recent developments and future perspectives.

Ever-growing demands for zinc-air batteries (ZABs) call for the development of advanced electrocatalysts. Single-atom catalysts (SACs), particularly those for isolating non-noble metals (NBMs), are attracting great interest due to their merits of low cost, high atom utilization efficiency, structural tunability, and extraordinary activity. Rational design of advanced NBM SACs relies heavily on an in-depth understanding of reaction mechanisms.

Nanostructure engineering of Pt/Pd-based oxygen reduction reaction electrocatalysts.

Increasing the atomic utilization of Pt and Pd elements is the key to the advancement and broad dissemination of fuel cells. Central to this task is the design and fabrication of highly active and stable Pt- or Pd-based electrocatalysts for the oxygen reduction reaction (ORR), which requires a comprehensive understanding of the ORR pathways and mechanism. Past endeavors have accumulated a wealth of knowledge about the Pt/Pd-based ORR electrocatalysts based on structure engineering, while a systematic review of the nanostructure engineering of Pt/Pd-based ORR electrocatalysts has been rarely reported.

Impact of molecular structure of starch on the glutinous taste quality of cooked chestnut kernels.

Chestnuts are a starchy food with a characteristic glutinous taste that is often used to assess their quality. In this study, our findings indicated that chestnuts with higher glutinous taste quality had lower amylose content and microcrystalline structures, as well as higher subcrystalline structures and relative crystallinity in both the raw and steamed starches. In the leached starch, chestnuts with higher glutinous taste quality had lower amylopectin B1 chains and microcrystalline structure, but higher amylopectin B2 chains, subcrystalline structure and relative crystallinity.

Recent advances of H-intercalated Pd-based nanocatalysts for electrocatalytic reactions.

The intercalation of H into Pd-based nanocatalysts plays a crucial role in optimizing the catalytic performance by tailoring the structural and electronic properties. We herein present a comprehensive review about the recent progress of interstitial hydrogen atom modified Pd-based nanocatalysts for various energy-related electrocatalytic reactions. Before systematically manifesting the great potential of Pd-based hydrides for electrocatalytic applications, we have briefly illustrated the synthesis strategies and corresponding mechanisms for the Pd-based hydrides.

MOF-derived single-atom catalysts for oxygen electrocatalysis in metal-air batteries.

Electrocatalysts play a critical role in oxygen electrocatalysis, enabling great improvements for the future development and application of metal-air batteries. Single-atom catalysts (SACs) derived from metal-organic frameworks (MOFs) are promising catalysts for oxygen electrocatalysis since they are endowed with the merits of a distinctive electronic structure, a low-coordination environment, quantum size effect, and strong metal-support interaction. In addition, MOFs afford a desirable molecular platform for ensuring the synthesis of well-dispersed SACs, endowing them with remarkably high catalytic activity and durability.

Insights into the effects of caffeic acid and amylose on in vitro digestibility of maize starch-caffeic acid complex.

Starch digestibility can be decreased by phenolic acids. The physicochemical and digestive properties of high-amylose maize starch, normal maize starch (NMS) and waxy maize starch (WMS) complexed with caffeic acid (CA) were investigated to determine the effects of CA and amylose on starch digestibility. CA inhibited the activity of α-glucosidase and α-amylase in a dose-dependent manner.

Effects of an Endophytic Fungus on the Secondary Metabolites of Host-Plant .

Fungal endophytes live widely inside plant tissues and some have been revealed to provide benefits to their host and ecological environment. Considering the fact that endophytes are engaged in remarkably stable long-term interactions with the host for their whole life cycle, it's conceivable that both partners have substantial influence on each other's metabolic processes. Here, we investigated the fermented products of an endophytic fungus SWUKD3.

Enhanced production of unusual triterpenoids from Kadsura angustifolia fermented by a symbiont endophytic fungus, Penicillium sp. SWUKD4.1850.

Highly oxygenated schitriterpenoids are interesting for study of their structures, bioactivities and synthesis. From Kadsura angustifolia fermented by an associated symbiotic endophytic fungus, Penicillium sp. SWUKD4.

An endophytic fungus from SWUKD3.1610 that produces nigranoic acid and its analogues.

The objective of this study was to determine whether endophytic fungi, isolated from produce nigranoic acid and its highly oxygenated derivatives. From the 426 endophytic fungi screened, SWUKD3.1610 was detected to have a component with the same TLC value and HPLC retention time as authentic nigranoic acid.