Synthesis, crystal structure and Hirshfeld surface analysis of a zinc(II) coordination polymer of 5-phenyl-1,3,4-oxa-diazole-2-thiol-ate.

A new zinc coordination polymer with 5-phenyl-1,3,4-oxa-diazole-2-thiol-ate, namely, -poly[zinc(II)-bis-(μ-5-phenyl-1,3,4-oxa-diazole-2-thiol-ato)-κ :;κ : ], [Zn(CHNOS)] , was synthesized. The single-crystal X-ray diffraction analysis shows that the polymeric structure crystallizes in the centrosymmetric monoclinic 2/ space group. The Zn atom is coordinated to two S and two N atoms from four crystallographically independent () ligands, forming zigzag chains along the [001] direction.