Vapor-Phase Contribution to Laser-Induced Plasma Emission of Magnesium in Liquid Aluminum.

Liquid aluminum containing the important alloying element magnesium in varying concentrations was analyzed using in-situ laser-induced breakdown spectroscopy (LIBS). Magnesium emission shows an exponential dependence on melt temperature that correlates well with the expected partial pressure of magnesium above the aluminum melt. Furthermore, comparison with LIBS measurements on corresponding solid samples supports the conclusion that a significant part of Mg emission from liquid metal samples originates from the vapor phase above the metal surface.