Effect of Chlorine Substituents on the Photovoltaic Properties of Monocyanated Quinoxaline-Based D-A-Type Polymers.

A string of monocyanated quinoxaline (Qx)-based D-A-type polymers systematically decorated with electron-attracting chlorine (Cl) atoms was created for use in non-fullerene polymer solar cells (PSCs). First, coupling of the benzodithiophene (BDT) donor and Qx acceptor with the strong electron-attracting cyano (CN) unit at its 5-position yielded the monocyanated reference polymer PB-CNQ. Subsequently, the additional Cl atoms were separately or simultaneously incorporated into the thiophene side groups of the BDT donor and Qx acceptor to create other objective polymers, PBCl-CNQ, PB-CNQCl, and PBCl-CNQCl.

Simple-Structured Low-Cost Dopant-Free Hole-Transporting Polymers for High-Stability CsPbIBr Perovskite Solar Cells.

Among the solution-processed devices, perovskite solar cells (PSCs) exhibit the highest power conversion efficiency (PCE) of over 25%; tremendous efforts are being undertaken to improve their stability. Recently, all-inorganic CsPbIBr-based PSCs were reported to exhibit a significantly improved device stability, with a promising PCE of up to 16.79%.

Nanostructured Hypercrosslinked Porous Organic Polymers: Morphological Evolution and Rapid Separation of Polar Organic Micropollutants.

Nanostructured hypercrosslinked porous organic polymers have triggered immense research interest for a broad spectrum of applications ranging from catalysis to molecular separation. However, it still remains a challenge to tune their nanoscale morphology. Herein, we demonstrated a remarkable variation of morphologies of triptycene-based hypercrosslinked microporous polymers starting from irregular aggregates (FCTP) to rigid spheres (SCTP) to two-dimensional nanosheets (SKTP) from three distinct polymerization methodologies, Friedel-Crafts knitting using an external crosslinker, Scholl reaction, and solvent knitting, respectively.

Multifunctional ionic porous frameworks for CO conversion and combating microbes.

Porous organic frameworks (POFs) with a heteroatom rich ionic backbone have emerged as advanced materials for catalysis, molecular separation, and antimicrobial applications. The loading of metal ions further enhances Lewis acidity, augmenting the activity associated with such frameworks. Metal-loaded ionic POFs, however, often suffer from physicochemical instability, thereby limiting their scope for diverse applications.

Excited-State Intramolecular Proton Transfer-Based Multifunctional Solid-State Emitter: A Fluorescent Platform with "Write-Erase-Write" Function.

The excited-state intramolecular proton transfer (ESIPT)-based molecular probes have drawn significant attention owing to their environment-sensitive fluorescence properties, large Stokes shift, and emerged as building blocks for the development of molecular sensors and switches. However, most of the ESIPT-based fluorophores exhibit weak emission in the solid state limiting the scope of real-time applications. Addressing such issues, herein, we presented a C symmetric-like molecular architecture employing a simple one-step Schiff base condensation between triaminoguanidinium chloride and 3,5-di- tert-butyl-2-hydroxybenzaldehyde (TGHB).

Redox-active, pyrene-based pristine porous organic polymers for efficient energy storage with exceptional cyclic stability.

A novel class of pyrene-based conjugated porous organic polymers having an N-containing network was developed by employing Buchwald-Hartwig coupling for supercapacitor energy storage. The pristine polymer was found to exhibit a specific capacitance of 456 F g-1 at 0.5 A g-1 current density with excellent long-term cyclic stability.

Microporous organic polymers involving thiadiazolopyridine for high and selective uptake of greenhouse gases at low pressure.

A new core of [1,2,5]-thiadiazolo-[3,4-c]-pyridine was employed for the fabrication of microporous organic polymers exhibiting a very high CO uptake of 5.8 mmol g (25.5 wt%) at 273 K and 1 bar.