Microalgae-derived biolubricants: Challenges and opportunities.

Lubricants are indispensable in the modern economy for controlling friction and wear across many industries. Traditional lubricants are derived from petroleum crude and can cause significant ecological impact if released into the environment. Microalgae have emerged as a potential alternative to petroleum crude for producing renewable and environmentally friendly biolubricants.

Optimising microplastics analysis for quantifying and identifying microplastic fibres in laundry wastewater.

Current methods for measuring microplastic fibres (MPF) are cumbersome, time consuming and unscalable for routine high throughput analysis. This study reports a method for rapidly extracting, quantifying and analysing MPFs in laundry wastewater with several key improvements which vastly enhance overall efficiency and scalability of analysis. FT-IR surveying is employed as a preliminary step in analysis to quickly determine what polymers are present in a sample prior to fluorescence treatment.

Recent Advances in High-Rate Solar-Driven Interfacial Evaporation.

Recent advances in solar-driven interfacial evaporation (SDIE) have led to high evaporation rates that open promising avenues for practical utilization in freshwater production and industrial application for pollutant and nutrient concentration, and resource recovery. Breakthroughs in overcoming the theoretical limitation of 2D interfacial evaporation have allowed for developing systems with high evaporation rates. This study presents a comprehensive review of various evaporator designs that have achieved pure evaporation rates beyond 4 kg m h, including structural and material designs allowing for rapid evaporation, passive 3D designs, and systems coupled with alternative energy sources of wind and joule heating.

Synthesizing cationic polymers and tuning their properties for microalgae harvesting.

This study reports a facile technique to synthesize and tune the cationic polymer, poly(3-acrylamidopropyl)trimethylammonium chloride (PAPTAC), in terms of molecular weight and surface change for harvesting three microalgae species (Scenedesmus sp., P.purpureum, and C.

Removal of Organics with Ion-Exchange Resins (IEX) from Reverse Osmosis Concentrate.

Reverse osmosis concentrate (ROC) produced as the by-product of the reverse osmosis process consists of a high load of organics (macro and micro) that potentially cause eco-toxicological effects in the environment. Previous studies focused on the removal of such compounds using oxidation, adsorption, and membrane-based treatments. However, these methods were not always efficient and formed toxic by-products.

Effects of Viscosity on Submerged Membrane Microfiltration Systems.

Submerged microfiltration has a wide range of applications in water and wastewater treatment. Membrane fouling is a major problem, resulting in a severe decline in flux, high energy consumption and frequent membrane cleaning and replacement. The effect of viscosity was not previously studied under controlled conditions to relate it to the air scour.

Metals extraction processes from electronic waste: constraints and opportunities.

The skyrocketing demand and progressive technology have increased our dependency on electrical and electronic devices. However, the life span of these devices has been shortened because of rapid scientific expansions. Hence, massive volumes of electronic waste (e-waste) is generating day by day.

Simultaneous nutrient recovery and algal biomass production from anaerobically digested sludge centrate using a membrane photobioreactor.

This study aims to evaluate the performance of C. vulgaris microalgae to simultaneously recover nutrients from sludge centrate and produce biomass in a membrane photobioreactor (MPR). Microalgae growth and nutrient removal were evaluated at two different nutrient loading rates (sludge centrate).

A comprehensive review on the framework to valorise lignocellulosic biomass as biorefinery feedstocks.

An effective pretreatment is the first step to enhance the digestibility of lignocellulosic biomass - a source of renewable, eco-friendly and energy-dense materials - for biofuel and biochemical productions. This review aims to provide a comprehensive assessment on the advantages and disadvantages of lignocellulosic pretreatment techniques, which have been studied at the lab-, pilot- and full-scale levels. Biological pretreatment is environmentally friendly but time consuming (i.

Biomethane production from anaerobic co-digestion and steel-making slag: A new waste-to-resource pathway.

A proof of concept of using steel-making slag to upgrade biogas to biomethane is demonstrated in this study. Biogas is generated from the anaerobic co-digestion of sewage sludge and beverage waste. The CO capture capacity of an alkaline liquor derived from the release of calcium from the steel-making slag is comparable to that of the commercial adsorbent monoethanolamine.

Derivation of volatile fatty acid from crop residues digestion using a rumen membrane bioreactor: A feasibility study.

This study evaluates the feasibility of a novel rumen membrane bioreactor (rumen MBR) to produce volatile fatty acids (VFA) from crop residues (i.e. lignocellulosic biomass).

Genome sequencing as a new window into the microbial community of membrane bioreactors - A critical review.

Recent developed sequencing techniques have resulted in a new and unprecedented way to study biological wastewater treatment, in which most organisms are uncultivable. This review provides (i) an insight on state-of-the-art sequencing techniques and their limitations; (ii) a critical assessment of the microbial community in biological reactor and biofouling layer in a membrane bioreactor (MBR). The data from high-throughput sequencing has been used to infer microbial growth conditions and metabolisms of microorganisms present in MBRs at the time of sampling.

Application of a novel molecular technique to characterise the effect of settling on microbial community composition of activated sludge.

Activated sludge (AS) and return activated sludge (RAS) microbial communities from three full-scale municipal wastewater treatment plants (denoted plant A, B and C) were compared to assess the impact of sludge settling (i.e. gravity thickening in the clarifier) and profile microorganisms responsible for nutrient removal and reactor foaming.

Improved photocatalysis of perfluorooctanoic acid in water and wastewater by GaO/UV system assisted by peroxymonosulfate.

Perfluorooctanoic acid (PFOA) has attracted considerable attention worldwide due to its widespread occurrence and environmental impacts. This research focused on the photocatalytic process for the treatment of PFOA in water and wastewater. Gallium oxide (GaO) and peroxymonosulfate (PMS) were mixed directly in PFOA solution, which was irradiated under different light sources.

Application of rumen and anaerobic sludge microbes for bio harvesting from lignocellulosic biomass.

This study investigated the production of biogas, volatile fatty acids (VFAs), and other soluble organic from lignocellulosic biomass by two microbial communities (i.e. rumen fluid and anaerobic sludge).

Removing arsenic from water by coprecipitation with iron: Effect of arsenic and iron concentrations and adsorbent incorporation.

Arsenic (As) contamination of drinking water is a major cause of As toxicity in many parts of the world. A study was conducted to evaluate As removal from water containing 100-700 μg/L of As and As to Fe concentration ratios of 1:5-1:1000 using the coprecipitation process with and without As/Fe adsorption onto granular activated carbon (GAC). Fe concentration required to reduce As concentrations in order to achieve the WHO standard level of 10 μg/L increased exponentially with the increase in initial As concentration.

Impacts of mixing on foaming, methane production, stratification and microbial community in full-scale anaerobic co-digestion process.

This study investigated the impact of mixing on key factors including foaming, substrate stratification, methane production and microbial community in three full scale anaerobic digesters. Digester foaming was observed at one plant that co-digested sewage sludge and food waste, and was operated without mixing. The lack of mixing led to uneven distribution of total chemical oxygen demand (tCOD) and volatile solid (VS) as well as methane production within the digester.

Sorptive removal of dissolved organic matter in biologically-treated effluent by functionalized biochar and carbon nanotubes: Importance of sorbent functionality.

The sorptive removal of dissolved organic matter (DOM) in biologically-treated effluent was studied by using multi-walled carbon nanotube (MWCNT), carboxylic functionalised MWCNT (MWCNT-COOH), hydroxyl functionalized MWCNT (MWCNT-OH) and functionalized biochar (fBC). DOM was dominated by hydrophilic fraction (79.6%) with a significantly lower hydrophobic fraction (20.

Sorption of hydrophobic organic contaminants on functionalized biochar: Protagonist role of π-π electron-donor-acceptor interactions and hydrogen bonds.

The sorption of five potent endocrine disruptors as representative hydrophobic organic contaminants (HOCs) namely estrone (E1), 17β-estradiol (E2), estriol (E3), 17α-ethynylestradiol (EE2) and bisphenol A (BPA) on functionalized biochar (fBC) was systematically examined, with a particular focus on the importance of π-electron-donor (phenanthrene: PHEN) and π-electron-acceptors (1,3-dinitrobenzene: DNB, p-amino benzoic acid: PABA) on sorption. Experimental results suggested that hydrogen-bond formation and π-π-electron-donor-acceptor (EDA) interactions were the dominant sorption mechanisms. The sorption of HOCs decreased as E1 > E2 > EE2 > E3 > BPA based on the Freundlich and Polanyi-Mane-models.

Photocatalysis of estrone in water and wastewater: Comparison between Au-TiO nanocomposite and TiO, and degradation by-products.

Gold-modified TiO (Au-TiO) photocatalysts were utilised for the degradation of estrone (E1), a major endocrine disrupting chemical in water and wastewater. Au-TiO catalysts were synthesised by a deposition-precipitation method with gold loadings of 0-8% (wt%). The Au-TiO nanocomposite exhibited superior activity compared to P25 TiO under UVA (λ=365nm), cool white (λ>420nm) and green (λ=523nm) light emitting diodes (LEDs), for treating 1mgl of E1.

Chloramphenicol interaction with functionalized biochar in water: sorptive mechanism, molecular imprinting effect and repeatable application.

Biochar and functionalized biochar (fBC-1 and fBC-2) were prepared and applied to remove antibiotic chloramphenicol from deionized water, lake water and synthetic wastewater. Results showed that chloramphenicol removal on biochar was pH dependent and maximum sorption occurred at pH4.0-4.

Rubidium extraction from seawater brine by an integrated membrane distillation-selective sorption system.

The ultimate goal of seawater reverse osmosis (SWRO) brine management is to achieve minimal liquid discharge while recovering valuable resources. The suitability of an integrated system of membrane distillation (MD) with sorption for the recovery of rubidium (Rb) and simultaneous SWRO brine volume reduction has been evaluated for the first time. Polymer encapsulated potassium copper hexacyanoferrate (KCuFC(PAN)) sorbent exhibited a good selectivity for Rb sorption with 10-15% increment at 55 °C (Langmuir Q = 125.

Competitive sorption affinity of sulfonamides and chloramphenicol antibiotics toward functionalized biochar for water and wastewater treatment.

Competitive sorption of sulfamethazine (SMT), sulfamethoxazole (SMX), sulfathiazole (STZ) and chloramphenicol (CP) toward functionalized biochar (fBC) was highly pH dependent with maximum sorption at pH ∼4.0-4.25.