Documented Orphaned Oil and Gas Wells Across the United States.

Orphaned oil and gas wells are unplugged nonproducing wells with no solvent owner of record to plug and mitigate them, such that the responsibility often falls on government agencies and the general public. Unplugged wells pose risks to the environment, climate, and human health. To develop a national framework to quantify the environmental benefits of plugging and optimize mitigation, we analyze oil and gas well data from state agencies across the United States to estimate the number of documented orphaned wells over time and evaluate their attributes.

New Mexico Permian Basin Measured Well Pad Methane Emissions Are a Factor of 5-9 Times Higher Than U.S. EPA Estimates.

Methane emission fluxes were estimated for 71 oil and gas well pads in the western Permian Basin (Delaware Basin), using a mobile laboratory and an inverse Gaussian dispersion method (OTM 33A). Sites with emissions that were below detection limit (BDL) for OTM 33A were recorded and included in the sample. Average emission rate per site was estimated by bootstrapping and by maximum likelihood best log-normal fit.

Gas-Phase Reactions of Isoprene and Its Major Oxidation Products.

Isoprene carries approximately half of the flux of non-methane volatile organic carbon emitted to the atmosphere by the biosphere. Accurate representation of its oxidation rate and products is essential for quantifying its influence on the abundance of the hydroxyl radical (OH), nitrogen oxide free radicals (NO ), ozone (O), and, via the formation of highly oxygenated compounds, aerosol. We present a review of recent laboratory and theoretical studies of the oxidation pathways of isoprene initiated by addition of OH, O, the nitrate radical (NO), and the chlorine atom.

Luminescence Quenching and Enhancement by Adsorbed Metal Ions with Ruthenium Diimine Complexes Immobilized on Silica Polyamine Composites.

Luminescent ruthenium diimine complexes have been covalently bound to the surface of a silica polyamine composite (SPC) using peptide coupling agents. The loading of the complexes using this route is quite low (~0.01-0.

Formation and evolution of molecular products in α-pinene secondary organic aerosol.

Much of our understanding of atmospheric secondary organic aerosol (SOA) formation from volatile organic compounds derives from laboratory chamber measurements, including mass yield and elemental composition. These measurements alone are insufficient to identify the chemical mechanisms of SOA production. We present here a comprehensive dataset on the molecular identity, abundance, and kinetics of α-pinene SOA, a canonical system that has received much attention owing to its importance as an organic aerosol source in the pristine atmosphere.

Vapor-wall deposition in chambers: theoretical considerations.

In order to constrain the effects of vapor-wall deposition on measured secondary organic aerosol (SOA) yields in laboratory chambers, researchers recently varied the seed aerosol surface area in toluene oxidation and observed a clear increase in the SOA yield with increasing seed surface area (Zhang, X.; et al. Proc.

Influence of vapor wall loss in laboratory chambers on yields of secondary organic aerosol.

Secondary organic aerosol (SOA) constitutes a major fraction of submicrometer atmospheric particulate matter. Quantitative simulation of SOA within air-quality and climate models--and its resulting impacts--depends on the translation of SOA formation observed in laboratory chambers into robust parameterizations. Worldwide data have been accumulating indicating that model predictions of SOA are substantially lower than ambient observations.

Midtrimester hemoperitoneum caused by placenta percreta in association with elevated maternal serum alpha-fetoprotein level.

We report a case of hemoperitoneum in the second trimester due to placenta percreta which was associated with an elevated maternal serum alpha-fetoprotein. A 29-year-old woman, gravida 4, para 1-0-2-1, was seen at 17 weeks' gestation with an acute abdomen. Maternal serum alpha-fetoprotein in a sample drawn 1 week previously revealed a value of 5.

Analysis of morbid events and risk factors for death after cardiac transplantation.

Risk factors for death after cardiac transplantation performed at the University of Alabama at Birmingham from January 1981 to July 1985 included (by multivariate analysis) higher calculated preoperative pulmonary vascular resistance (early and constant phases), morphology of cardiomyopathy (versus ischemic heart disease) (constant phase only) and black race (constant phase). Overall actuarial survival was 71% at 1 year and 48% at 3 years (including azathioprine and cyclosporine eras). The hazard function for death was highest immediately after operation and declined rapidly thereafter, merging with a constant phase of risk at about 3 months.

Conversion from cyclosporine to azathioprine following heart transplantation.

Eleven patients receiving cyclosporine were converted to azathioprine immunosuppression because of persistent creatinine elevation greater than 2 mg/dl 6 months or more following heart transplantation. During conversion, the maintenance steroid dose was doubled for 3 months then tapered to the preconversion dose. Pretransplant renal function in these converted patients was similar to that in a group of azathioprine patients and a group of nonconverted cyclosporine patients.