Modeling of the viscoelastic behavior of dental light-activated resin composites during curing.

Objective: Three models consisting of springs and dashpots were investigated to describe the viscoelastic behavior of a commercial light-activated restorative composite during curing.

Methods: Stress-strain data on Z100 were recorded by means of a dynamic test method performed on a universal testing machine. The model was tested by matching its response to experimental data and the material parameters, E (Young's modulus) and eta (viscosity), associated with the model were calculated.

Bonding Properties of a Novel Inorganometallic Complex, Ru(SnPh(3))(2)(CO)(2)(iPr-DAB) (iPr-DAB = N,N'-Diisopropyl-1,4-diaza-1,3-butadiene), and its Stable Radical-Anion, Studied by UV-Vis, IR, and EPR Spectroscopy, (Spectro-) Electrochemistry, and Density Functional Calculations.

Ru(SnPh(3))(2)(CO)(2)(iPr-DAB) was synthesized and characterized by UV-vis, IR, (1)H NMR, (13)C NMR, (119)Sn NMR, and mass (FAB(+)) spectroscopies and by single-crystal X-ray diffraction, which proved the presence of a nearly linear Sn-Ru-Sn unit. Crystals of Ru(SnPh(3))(2)(CO)(2)(iPr-DAB).3.