Publications by authors named "Max S Guerry"
Org Biomol Chem
December 2019
Article Synopsis
- - A study was conducted on various triazolium salts to measure their acidity, specifically their pKa values, in DMSO at 25 °C using a method involving bracketing indicators.
- - The research focused on how different structural changes affected the acidity of the triazolium cation, with an emphasis on electronic properties determined by Hammett σ parameters.
- - Unique findings include the first reported pKa value for an azolium salt that produces a mesionic carbene, which aids in selecting suitable bases for deprotonating these salts and linking pKa values to the reactivity of the resulting carbenes.
